Products bearing the AP seal of the Art & Creative Materials Institute, Inc. (ACMI) are certified non-toxic. A product can be certified non-toxic only if it contains no materials in sufficient quantities to be toxic or injurious to humans, or to cause acute or chronic health problems when used as intended. See [Health and Safety ](https://www.dickblick.com/learning-resources/product-info/health-safety/ "Learning-resources/product-info/health-safety")for further information.
Products bearing the AP seal of the Art & Creative Materials Institute, Inc. (ACMI) are certified non-toxic. A product can be certified non-toxic only if it contains no materials in sufficient quantities to be toxic or injurious to humans, or to cause acute or chronic health problems when used as intended. See [Health and Safety ](https://www.dickblick.com/learning-resources/product-info/health-safety/ "Learning-resources/product-info/health-safety")for further information.
Due to differences in users’ monitors, the colors presented are an approximation of the true color.
PBL9-Bone Black
PW6-Titanium White
PBr7-Burnt Sienna
PW4-Zinc White
PBL9-Bone Black
inorganic/organic
carbon
C
Bone Black is a carbon black pigment produced from charring animal bones, usually done at high temperature in a kiln, similar to Ivory Black.
Bone Black is absolutely permanent.
Bone Black is non-toxic, provided that it does not contain harmful impurities.
Bone Black has been used as a source of pigment since prehistoric times. It has been detected in paintings back to the Middle Ages.
PW6-Titanium White
inorganic
titanium dioxide
TiO2
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Titanium White has excellent permanence and lightfastness.
Titanium dioxide is highly stable and is regarded as non-toxic.
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
PBr7-Burnt Sienna
earth
iron oxides
Fe2O3
Burnt Sienna is a warm, mid-brown color formed by burning the yellow-brown limonite clay called Raw Sienna. It ranges from semi-opaque to semi-transparent due to the combination of its opaque, red-brown mass tone and its transparent, orangey undertone. It is an excellent mixing complement for blues and greens and creates salmon or peach colored tints when mixed with white. It can be useful for subduing bright colors and does not get chalky in dark mixtures.
Burnt Sienna has good permanence and is considered one of the most versatile of the permanent pigments.
Burnt Sienna has no significant hazards.
Burnt Sienna has been used as a pigment since prehistoric times, but its current name came about during the Renaissance. It comes from the city of Siena, in Italy, and is short for terra di Siena, meaning earth of Siena. Sienna was famous for the mining and production of earth pigments from the Renaissance until World War II. Due to the depletion of clay deposits in Tuscany, Italian siennas now come from other areas, including Sicily and Sardinia.
PW4-Zinc White
inorganic
zinc(II)-oxide
ZnO
Zinc White is the coolest white, and it has a cold, clean masstone and a slightly bluish tint. It has less hiding power and is more transparent than other whites. It dries slowly and is good for painting wet into wet and for glazing and scumbling. Zinc White is neither as opaque nor as heavy as Lead White, its covering power is not as good, and it takes much longer to dry. However, it does not blacken when exposed to sulfur in the air as Lead White does. It is very valuable for making tints with other colors. Unmixed Zinc White dries to a brittle and dry paint film that may crack over the years, so it is not good for frescoing. It is more transparent in acrylic form than Titanium White and is the most commonly used white with gouache. Chinese White is a version of Zinc White appropriate for opaque watercolor techniques.
Zinc White has great permanence and lightfastness.
Zinc White is moderately toxic if ingested and slightly toxic if inhaled.
Though historians are divided on who first isolated the element zinc, they agree that it was first suggested as a white pigment in 1782. Zinc White was accepted as a watercolor in 1834 and was called Chinese White due to the popularity of oriental porcelain in Europe at the time. Ten years later, a suitable oil form was produced. By the early 20th century, it had improved to the point where it was an acceptable alternative to Flake White.
UPC Code: 8715046020739
ASIN #: B005WK0FOY