Old Holland Classic Artist Watercolor - Old Holland Yellow Medium, 6 ml tube

Pigment Information

This color contains the following pigments:

PY74-Hansa Yellow

PR108-Cadmium Red

PW4-Zinc White

Pigment Name

PY74-Hansa Yellow

Pigment Type

monoazo

Chemical Formula

C18H18N4O6

Properties

Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.

Permanence

This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.

Toxicity

Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.

Pigment Name

PR108-Cadmium Red

Pigment Type

inorganic, cadmium

Chemical Name

cadmium sulfide and cadmium selenide

Chemical Formula

CdS x CdSe

Properties

Cadmium Red is a bright, warm red that ranges in shade from orange-red to maroon and is available in light, medium, and dark versions. It is strong and opaque, with good tinting strength. Cadmium Red dries slowly. It grays down when mixed with white, mixes well with blues to create a range of browns, and mixes well with Cadmium Yellow to create a strong orange. It also works well in neutral mixes. Cadmium pigments have been partially replaced by azo pigments, which are similar in lightfastness to the cadmium colors, cheaper, and non-toxic. Hues vary by brand. Cadmium Red is usually available in either a pure grade or a cadmium-barium mix. The cadmium-barium mix has the same permanence as pure Cadmium Red, but it has a lower tinting strength.

Permanence

Cadmium Red is lightfast and permanent in most forms, but like many cadmium pigments, it will fade in fresco or mural painting. Its improved lightfastness has helped it to replace Vermilion on the artist’s palette.

Toxicity

Cadmium Red is a known human carcinogen. It is extremely toxic if inhaled and slightly toxic if ingested.

History

Cadmiums get their names from the Latin word cadmia meaning zinc ore calamine, and the Greek word kadmeia, meaning Cadmean earth, first found near Thebes, the city founded by the Phoenician prince Cadmus. Metallic cadmium was discovered in 1817 by Friedrich Strohmeyer, but Cadmium Red was not introduced until 1907 in Germany.

Pigment Name

PW4-Zinc White

Pigment Type

inorganic

Chemical Name

zinc(II)-oxide

Chemical Formula

ZnO

Properties

Zinc White is the coolest white, and it has a cold, clean masstone and a slightly bluish tint. It has less hiding power and is more transparent than other whites. It dries slowly and is good for painting wet into wet and for glazing and scumbling. Zinc White is neither as opaque nor as heavy as Lead White, its covering power is not as good, and it takes much longer to dry. However, it does not blacken when exposed to sulfur in the air as Lead White does. It is very valuable for making tints with other colors. Unmixed Zinc White dries to a brittle and dry paint film that may crack over the years, so it is not good for frescoing. It is more transparent in acrylic form than Titanium White and is the most commonly used white with gouache. Chinese White is a version of Zinc White appropriate for opaque watercolor techniques.

Permanence

Zinc White has great permanence and lightfastness.

Toxicity

Zinc White is moderately toxic if ingested and slightly toxic if inhaled.

History

Though historians are divided on who first isolated the element zinc, they agree that it was first suggested as a white pigment in 1782. Zinc White was accepted as a watercolor in 1834 and was called Chinese White due to the popularity of oriental porcelain in Europe at the time. Ten years later, a suitable oil form was produced. By the early 20th century, it had improved to the point where it was an acceptable alternative to Flake White.