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PW18-Calcium Carbonate
PB29-Ultramarine [Blue]
PB27-Antwerp Blue
PBk6-Lamp Black
PW18-Calcium Carbonate
inorganic
calcium carbonate
CaCO3
Calcium carbonate, the mineral constituent of chalk, is a low tinting strength, inexpensive white pigment that is often used is a buffer and filler. Because of its low tinting strength, it is overwhelmed by other colors. It is used in gesso and other coatings to give the surface more tooth, a desirable characteristic for some painting techniques.
Calcium carbonate is lightfast. Like all carbonates, it reacts with strong acids
Calcium carbonate is completely non-toxic, and is used in many food, cosmetic, and pharmaceutical products. However, excessive consumption is not recommended.
Naturally occuring chalk deposits have been mined since prehistoric times. Rocks and minerals that contain calcium carbonate include aragonite, calcite, vaterite, chalk, limestone. marble, and travertine. Calcium carbonate is the principle component of lime, used in many agricultural and industrial applications.
PB29-Ultramarine [Blue]
inorganic
complex silicate of sodium and aluminum with sulfur
Na8-10Al6Si6O24S2-4 or Na6-8Al6Si6O24S2-4
Ultramarine is the standard warm blue, a brilliant blue pigment that has the most purple and least green in its undertone. It has a moderate to high tinting strength and a beautiful transparency. Synthetic Ultramarine is not as vivid a blue as natural Ultramarine. Ultramarine dries slowly in oil and tends to produce clean, though granular, washes in watercolor. French Ultramarine mixes well with Alizarin colors in oil and watercolor form to create a range of purples and violets. It can dull when mixed with white in acrylic form, but mixes well with other colors. The shade varies based on manufacturer. Considered a great color for glazes, it is not suitable for frescoing.
Ultramarine has excellent permanence, although synthetic Ultramarine is not as permanent as natural Ultramarine. It may discolor if exposed to acid because of its sulfuric content.
Ultramarine has no significant hazards.
The name for this pigment comes from the Middle Latin ultra, meaning beyond, and mare, meaning sea, because it was imported from Asia to Europe by sea. It is a prominent component of lapis lazuli and was used on Asian temples starting in the 6th century. It was one of the most expensive pigments in 16th century Europe, worth twice its weight in gold, and so was used sparingly and when commissions were larger. Ultramarine is currently imitated by a process invented in France in 1826 by Jean Baptiste Guimet, making blue affordable to artists and extending the range of colors on their palettes.
PB27-Antwerp Blue
inorganic
ferric ammonium ferrocyanide
C18Fe7N18
Antwerp Blue is a slightly warm and less saturated blue with good transparency and undertone clarity. It is a pale variety of Prussian Blue with 75% inert pigment. It has similar properties to pure Prussian Blue, but its overall performance is inferior.
Antwerp Blue can fluctuate, fading in the light and recovering in the dark. In watercolor form, it fades when mixed with white pigment or extender. Although it has reasonably good lightfastness and permanence, it is not considered ideal for permanent painting.
Antwerp Blue is mildly toxic by ingestion, but is considered safe for external use. In the United States, ferric ferrocyanide is permitted as a coloring ingredient for externally applied cosmetics, but not for lipsticks or internal use. If the pigment is
Antwerp Blue was developed through experimentation with Prussian Blue.
PBk6-Lamp Black
inorganic
carbon
C
Lamp black is a very opaque, heavily staining black pigment that does not have much covering power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures, is one of the slowest drying pigments in oils, and should not be used under other colors.
Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.
Lamp Black is slightly toxic by skin contact and inhalation. It is a possible human carcinogen.
Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It is the black found in Egyptian murals and tomb decorations and was the most popular black for frescoing until the development of Mars Black.