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PW18-Calcium Carbonate
PBr7-Burnt Umber
PO23-Cadmium Orange
PW18-Calcium Carbonate
inorganic
calcium carbonate
CaCO3
Calcium carbonate, the mineral constituent of chalk, is a low tinting strength, inexpensive white pigment that is often used is a buffer and filler. Because of its low tinting strength, it is overwhelmed by other colors. It is used in gesso and other coatings to give the surface more tooth, a desirable characteristic for some painting techniques.
Calcium carbonate is lightfast. Like all carbonates, it reacts with strong acids
Calcium carbonate is completely non-toxic, and is used in many food, cosmetic, and pharmaceutical products. However, excessive consumption is not recommended.
Naturally occuring chalk deposits have been mined since prehistoric times. Rocks and minerals that contain calcium carbonate include aragonite, calcite, vaterite, chalk, limestone. marble, and travertine. Calcium carbonate is the principle component of lime, used in many agricultural and industrial applications.
PBr7-Burnt Umber
earth
iron oxides with manganese silicates or dioxide
Fe2O3,MnO2 or Fe2O3+MnO2+nH2O+Si+Al2O3
Burnt Umber is a more intense reddish brown pigment that results from heating the clay pigment Raw Umber. It has medium to excellent tinting strength and high opacity, and it is quick drying in oil form. Burnt Umber is somewhat more transparent than Raw Umber. It has excellent color properties and can create a variety of subtle, clear tints when mixed with white. It can tend towards chalkiness in dark mixes in oil form, but overall it mixes well with other colors. To create a black color in oil form, mix Burnt Umber with Phthalo Blue or Ultramarine. To achieve a similar color in watercolor form, mix it with Ultramarine or Payne's Gray.
Burnt Umber has good permanence.
Burnt Umber itself is considered non-toxic. If contaminated by manganese compounds, it may be highly toxic if inhaled and moderately toxic if ingested.
This pigment gets its name from the Latin word umbra, meaning shadow or shade. Its full name is listed as terra di ombra, meaning earth of shadow/shade, due to its original extraction from the area of Umbria, Italy. It has been used as a pigment since prehistoric times. Currently, the finest umber comes from Cyprus.
PO23-Cadmium Orange
inorganic, cadmium
cadmium sulfide and cadmium selenide
CdS × CdSe
Cadmium Orange was the first true orange and was made by mixing Cadmium Yellow with Cadmium Red. It is a pure hue with excellent opacity and low toxicity compared with its predecessors. It also has very high hiding power. The greatest tinting strengths are possessed by the deeper shades. Only the highest grades contain pure Cadmium Orange without barium mixed in it. Cadmium pigments have been partially replaced by azo pigments, which are similar in lightfasness to the cadmium colors, cheaper, and non-toxic.
Cadmium Orange has excellent permanence, but like many cadmium pigments, it will fade in fresco or mural painting. The deeper varieties of this pigment are the most permanent. The paler varieties have been known to fade when exposed to sunlight. Cadmium pigments are not recommended for outdoor painting.
Cadmium Orange is a known human carcinogen. It is extremely toxic if inhaled and slightly toxic if ingested.
Cadmiums get their names from the Latin word cadmia, meaning zinc ore calamine, and the Greek word kadmeia, meaning Cadmean earth, first found near Thebes, the city founded by the Phoenician prince Cadmus. Metallic cadmium was discovered in 1817 by Friedrich Strohmeyer. It was used sparingly after its discovery due to the scarcity of cadmium metal.