C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)
Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules. Pigment PG36 differs from PG7 in that a portion of the chlorine atoms are replaced with bromine atoms, which are reactively similar, but cause a yellow shift that is especially noticeable in mixtures. Phthalo Green has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors. This pigment most closely resembles the discontinued and toxic Verdigris.
Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.
Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.
This bright blue-green was developed in 1935 and has been in use since 1938.
charred animal bone
carbon + calcium phosphate
C + Ca3(PO4)2 or C x CaPO4
Ivory Black is a cool, semi-transparent blue-black with a slight brownish undertone and average tinting strength. It mixes well with any color, and creates a range of dull greens when mixed with yellow. It has good properties for use in oil, can be slow to dry in oil form, and should never be used in underpainting or frescoing. Ivory Black is denser than Lamp Black.
Ivory Black is very lightfast and has good permanence, though it is considered the least permanent of the major black pigments.
Ivory Black has no significant hazards.
Ivory Black is a carbon based black first named as Elephantium, and described in the 4th century BCE as produced by heating ivory scraps in clay pots to reduce the ivory or bone to charcoal. The deviation in names is because the more expensive varieties of this pigment were made by burning ivory, and the less expensive ones by burning animal bone. In the 19th century, the name Ivory Black was finally permitted to be applied to Carbon Black pigments made from bone. True Ivory Black is rare in modern times due to the protection of ivory, and the synthetic variety produced today was discovered in 1929. Bone Black is produced as an industrial pigment.
PY150-Nickel Azo Yellow
nickel azomethine yellow
Nickel Azo Yellow is a transparent, moderately staining yellow pigment with high tinting strength. It is considered a good color match in botanical and landscape painting for natural gamboge (NY24), a historic yellow pigment with fair to poor lightfastness.
Nickel azomethine yellow has excellent lightfastness.
Nickel azo yellow pigment is mildly toxic, and is often labeled as hazardous. Avoid respiratory and skin exposure to pigment dust. It should be disposed of properly with other hazardous wastes, not washed down the sink.
Nickel azomethine yellow has been developed as an artist pigment becasue it is a close match for gamboge, a historic yellow.