Holbein Artists' Soft Pastel - Old Rose 3

Pigment Information

This color contains the following pigments:

PBk11-Mars Black

PR122-Quinacridone Magenta

PW6-Titanium White

PR101-Red Iron Oxide

Pigment Name

PBk11-Mars Black

Pigment Type

earth

Chemical Name

iron oxides

Chemical Formula

FeO or Fe2O3

Properties

Mars Black is an opaque black with a strong and cool masstone, a slightly warm tint, and a warm brown undertone. It is not as black as Ivory Black, but it dries more quickly and has three times the tinting strength. Mars Black is normally the only black available in acrylic form and that is safe to over paint. It can be used in all media without reservation and is widely used as an alternative to Lamp Black and Ivory Black.

Permanence

Mars Black is very lightfast with excellent permanence.

Toxicity

Mars Black has no significant hazards and is the only major black pigment considered non-toxic.

History

The word Mars refers to the Roman god of iron and war. Mars Black was developed in the early 20th century from inorganic, synthetic iron oxide.

Pigment Name

PR122-Quinacridone Magenta

Pigment Type

organic, quinacridone

Chemical Formula

C22H16N2O2

Properties

Quinacridone Magenta is a semi-transparent and powerful bluish red with an impressive mixing range. It makes an excellent glazing color and is one of the bluest of the Quinacridone colors. The pigment's properties vary considerably, depending on how it is ground. Quinacridone pigments have relatively low tinting strength in general. For this reason, quinacridone colors are often expensive, because more pigment is required in the formulation.

Permanence

Quinacridone Magenta offers very good lightfastness in most media, but some have argued that it is less lightfast in watercolor form. Although Quinacridone Magenta received only a passing grade of "fair" under ASTM test protocols, other test results have rated the pigment very good to excellent. Transparent reddish violet pigments in general have more problems with lightfastness than any other range of colors. PR122 is often used as the Magenta of CMYK (four color) process printing because it offers a better tradeoff between tinting strength and lightfastness than other pigments in its class.

Toxicity

Quinacridone Magenta has no acute hazards. Overexposure to quinacridone pigments may cause skin irritation. Quinicridone pigments contain a compound found to be a skin, eye, and respiratory irritant.

History

Quinacridone Magenta came from a red violet aniline dye that was first produced in 1858 by Natanson. It was called Magenta to commemorate a battle in Magenta, Italy. Over time, Magenta became the standard color name for a deep, violet red. Although quinacridone compounds became known in the late 19th century, methods of manufacturing so as to make them practical for use as commercial pigments did not begin until the 1950s. PR122 has become particularly popular in the formulation of Magenta for CMYK process printing.

Pigment Name

PW6-Titanium White

Pigment Type

inorganic

Chemical Name

titanium dioxide

Chemical Formula

TiO2

Properties

Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.

Permanence

Titanium White has excellent permanence and lightfastness.

Toxicity

Titanium dioxide is highly stable and is regarded as non-toxic.

History

Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.

Pigment Name

PR101-Red Iron Oxide

Pigment Type

earth, synthetic

Chemical Name

iron oxides (synthetic), iron oxide, silica, alumina, lime, and magnesia or hydrated iron oxide

Chemical Formula

Fe2O2 or Fe2O3 x H2O

Properties

Red iron oxide varies in hue and transparency, depending on hydration and slight impurities. Indian Red is a slightly duller, deep brick hue with a bluish undertone. It is very dense and opaque, with excellent tinting strength and covering power. It is dependable when mixing with all other permanent pigments and yields good flesh tints when mixed with Zinc White. It is the synthetic version of PR102, which is a pigment made from earth reds, or natural red iron oxides, and the names applied to PR101 and PR102 often overlap. The synthetic red iron oxides have mostly replaced natural red iron oxides and are brighter, stronger, finer, and more permanent. Indian Red is the highest grade bluish shade. Light Red, English Red, and Venetian Red are yellowish shades. Mars Violet is a dull and subdued bluish or purplish oxide.

Permanence

Red iron oxide is very lightfast with excellent permanence.

Toxicity

Red iron oxide has no significant hazards.

History

Natural red iron oxide comes from the mineral ore hematite, called bloodstone by the ancient Greeks from the word hema, meaning blood. It is one of the oldest pigments, has been used by every major civilization, and was an important mineral for medieval alchemists. It was not widely used in artists' materials until the 17th century and was not produced in large quantities until the 18th century.