Daniel Smith Extra Fine Watercolor - Naples Yellow, 5 ml Tube

Pigment Information

This color contains the following pigments:

PY97-Permanent Yellow

PR101-Red Iron Oxide

PW4-Zinc White

Pigment Name

PY97-Permanent Yellow

Pigment Type

organic, monoazo

Chemical Formula

C26H27ClN4O8

Properties

Permanent Yellow PY97 ranges from reddish yellow to greenish yellow with temperature shifts from cool to warm hues. It has good tinting strength and average to slow drying time. Similar in shade to Hansa Yellow 1, it offers much better fastness properties and good heat stability.

Permanence

Pigment PY97 has excellent lightfastness, particularly in the darker shades.

Toxicity

No significant acute hazards of PY97 are known, though chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow. Permanent Yellow (PY97) represents a further development of this line, with the aim of producing a yellow pigment that is suitable for exterior use.

Pigment Name

PR101-Red Iron Oxide

Pigment Type

earth, synthetic

Chemical Name

iron oxides (synthetic), iron oxide, silica, alumina, lime, and magnesia or hydrated iron oxide

Chemical Formula

Fe2O2 or Fe2O3 x H2O

Properties

Red iron oxide varies in hue and transparency, depending on hydration and slight impurities. Indian Red is a slightly duller, deep brick hue with a bluish undertone. It is very dense and opaque, with excellent tinting strength and covering power. It is dependable when mixing with all other permanent pigments and yields good flesh tints when mixed with Zinc White. It is the synthetic version of PR102, which is a pigment made from earth reds, or natural red iron oxides, and the names applied to PR101 and PR102 often overlap. The synthetic red iron oxides have mostly replaced natural red iron oxides and are brighter, stronger, finer, and more permanent. Indian Red is the highest grade bluish shade. Light Red, English Red, and Venetian Red are yellowish shades. Mars Violet is a dull and subdued bluish or purplish oxide.

Permanence

Red iron oxide is very lightfast with excellent permanence.

Toxicity

Red iron oxide has no significant hazards.

History

Natural red iron oxide comes from the mineral ore hematite, called bloodstone by the ancient Greeks from the word hema, meaning blood. It is one of the oldest pigments, has been used by every major civilization, and was an important mineral for medieval alchemists. It was not widely used in artists' materials until the 17th century and was not produced in large quantities until the 18th century.

Pigment Name

PW4-Zinc White

Pigment Type

inorganic

Chemical Name

zinc(II)-oxide

Chemical Formula

ZnO

Properties

Zinc White is the coolest white, and it has a cold, clean masstone and a slightly bluish tint. It has less hiding power and is more transparent than other whites. It dries slowly and is good for painting wet into wet and for glazing and scumbling. Zinc White is neither as opaque nor as heavy as Lead White, its covering power is not as good, and it takes much longer to dry. However, it does not blacken when exposed to sulfur in the air as Lead White does. It is very valuable for making tints with other colors. Unmixed Zinc White dries to a brittle and dry paint film that may crack over the years, so it is not good for frescoing. It is more transparent in acrylic form than Titanium White and is the most commonly used white with gouache. Chinese White is a version of Zinc White appropriate for opaque watercolor techniques.

Permanence

Zinc White has great permanence and lightfastness.

Toxicity

Zinc White is moderately toxic if ingested and slightly toxic if inhaled.

History

Though historians are divided on who first isolated the element zinc, they agree that it was first suggested as a white pigment in 1782. Zinc White was accepted as a watercolor in 1834 and was called Chinese White due to the popularity of oriental porcelain in Europe at the time. Ten years later, a suitable oil form was produced. By the early 20th century, it had improved to the point where it was an acceptable alternative to Flake White.