Caran d'Ache Neocolor I Wax Pastel - Brown

Pigment Information

This color contains the following pigments:

PB15-Phthalo Blue

PO62-Benzimidazolone Orange

PR112-Naphthol Red AS-D

PY42-Yellow Iron Oxide

PY3-Hansa Yellow 10G

Pigment Name

PB15-Phthalo Blue

Pigment Type

organic

Chemical Name

copper phthalocyanine

Chemical Formula

C32H16CuN8

Properties

Phthalo Blues are pure and clean primary blues with superior covering power. They have a very high tinting strength and tend to overwhelm other pigments, but if color strength can be controlled, they make predictable mixed colors. In oil form, blues are very deep and slow drying. When mixed with other colors or if chlorine is added, Phthalo Blue quickly tends towards green. When using alone, mix with some white, as Phthalo Blue can be semi-transparent and almost black on its own. It is among the most compatible of modern colors with mineral colors and is considered more reliable than Prussian Blue, while sharing the same physical and color properties. Phthalo Blue is a good color for glazing.

Permanence

Phthalo Blues are completely lightfast and stable and are permanent for all paint uses. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.

Toxicity

Phthalo Blues have no significant hazards, although those made before 1982 contained some PCBs (polychlorinated biphenyls).

History

Developed by chemists using the trade name Monastral Blue, the organic blue dyestuff now known as Phthalo Blue was presented as a pigment in November 1935 in London. Its discovery was accidental. The dark color was observed in a kettle where a dye was being made from a British dyestuff plant. The demand for such a pigment came from commercial printers who wanted a cyan to replace Prussian Blue.

Pigment Name

PO62-Benzimidazolone Orange

Pigment Type

organic, monoazo

Chemical Formula

C17H13ClN6O5

Properties

Benzimidazolone Orange is a staining, yellowish orange pigment that can become dull in tints. It has an average drying time, and it loses some of its intensity as it dries. The yellowish orange varieties are more transparent.

Permanence

Benzimidazolone Orange has excellent lightfastness and outstanding heat and solvent stability for a monoazo pigment.

Toxicity

Benzimidazolone Orange is not considered toxic.

History

The benzimidazolone group of pigments was developed and patented in 1960 by Hoechst A.G., a German chemical manufacturer that was a forerunner of the pharmaceutical company Aventis. Use of benzimidazolone pigments in the auto industry, especially Benzimidazolone Orange, became common in the 1980s because they were common replacements for lead chromate pigments, which were phased out during this period.

Pigment Name

PR112-Naphthol Red AS-D

Pigment Type

organic, monoazo

Chemical Formula

C24H16Cl3N3O2

Properties

This Naphthol Red is an intense scarlet red pigment that is heavily staining. It has an average drying time. It is semi-transparent and has relatively poor covering power.

Permanence

This Naphthol Red has been rated as having excellent lightfastness under ASTM testing, but other testing methods have demonstrated some tendancy for the color to fade with exposure to strong ultraviolet light. It has been considered a replacement for less lightfast naphthol reds such as PR3. Not suitable for exterior use.

Toxicity

Naphthol Reds are not considered toxic. Naphthol Red AS-D may cause eye, skin, or respiratory irritation. Contact with dry pigment should be avoided.

History

Unknown.

Pigment Name

PY42-Yellow Iron Oxide

Chemical Name

iron(III)-oxide, hydrated

Chemical Formula

Fe2O3 • H2O

Properties

Yellow Ochre provides artists with earthtones from cream to brown. It has good hiding power, produces a quick drying paint, and can be safely mixed with other pigments. Its transparency varies widely from opaque shades to more transparent ones, which are valued for their use as glazes. If gypsum is present, Yellow Ochre is not suitable for frescoing. (See Brown Ochre, PY43.) PY42 is made from synthetic iron oxides. PY43 is made from natural iron oxide.

Permanence

Yellow Ochre has excellent permanence because ochres are some of the most permanent pigments available.

Toxicity

Yellow Ochre is non-toxic unless it contains manganese.

History

Ochre comes from the Greek word ochros, meaning pale yellow. It was one of the first pigments to be used by human beings, and evidence of its use has been found at 300,000 year old sites in France and the former Czechoslovakia.

Pigment Name

PY3-Hansa Yellow 10G

Pigment Type

organic, monoazo

Chemical Formula

C16H12CL2N4O2

Properties

This Hansa yellow is a transparent yellow. It has great brightness and tinting strength and its drying time ranges from average to slow. Hansa Yellow makes more intense tints and cleaner secondaries than Cadmium Yellows, especially when mixed with other organic or modern colors like Phthalo Blue and Green. Because they are more transparent, they have great value as glazing colors.

Permanence

This Hansa Yellow has fair to good permanence, particularly in the lighter shades.

Toxicity

Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.