Grumbacher Academy Oil Color - Cadmium Red Deep Hue, 37 ml tube

Pigment Information

This color contains the following pigments:

PR170-Naphthol Red

PY74-Hansa Yellow

PR112-Naphthol Red AS-D

PR149-Perylene Red

PR101-Red Iron Oxide

Pigment Name

PR170-Naphthol Red

Pigment Type

organic, naphthol AS

Chemical Formula

C26H22N4O4

Properties

Pigment PR170 is a bright deep red with bluish undertones. It has an average drying time. It has two crystaline forms that differ significantly in opacity. The more transparent form (F5RK) tends to be more bluish and is less lightfast.

Permanence

The lightfastness and weatherfastness of Pigment PR170 varies, depending on the application and the crystaline form. The opaque form (F3RK) has very good lightfastness, and is more weather resistant. The transparent form (F5RK) has lightfastness that is considered acceptable in pure applications, but it fades more in tints. Neither form is considered suitable for exterior use.

Toxicity

Naphthol Reds are not considered toxic. They may cause eye, skin, or respiratory irritation. Contact with dry pigment should be avoided.

History

Naphthol pigments are actually dyes that are "laked" to form pigments. First developed by the German chemical company Hoechst A.G. before World War I, their use in artist paints began in the 1920s. Pigment Red PR170 is a Naphthol AS pigment, chemically related to the diarylide yellow pigments. The Naphthol AS pigments comprise a range of reds. They are used in plastics, textiles, and printing inks.

Pigment Name

PY74-Hansa Yellow

Pigment Type

monoazo

Chemical Formula

C18H18N4O6

Properties

Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.

Permanence

This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.

Toxicity

Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.

Pigment Name

PR112-Naphthol Red AS-D

Pigment Type

organic, monoazo

Chemical Formula

C24H16Cl3N3O2

Properties

This Naphthol Red is an intense scarlet red pigment that is heavily staining. It has an average drying time. It is semi-transparent and has relatively poor covering power.

Permanence

This Naphthol Red has been rated as having excellent lightfastness under ASTM testing, but other testing methods have demonstrated some tendancy for the color to fade with exposure to strong ultraviolet light. It has been considered a replacement for less lightfast naphthol reds such as PR3. Not suitable for exterior use.

Toxicity

Naphthol Reds are not considered toxic. Naphthol Red AS-D may cause eye, skin, or respiratory irritation. Contact with dry pigment should be avoided.

History

Unknown.

Pigment Name

PR149-Perylene Red

Pigment Type

organic, anthraquinone

Chemical Formula

C40H26N2O6

Properties

Perylene Red is a moderately intense, semi-opaque, medium red pigment, appearing somewhere between a Cadmium Red and a Cadmium Deep Red hue. It has excellent brightness and tinting strength. Its partial transparency makes it useful as a glazing color.

Permanence

Perylene Red has good lightfastness and permanence. Its tints may darken after extended exposure to sunlight. It is not considered suitable for exterior use.

Toxicity

Perylene Red has no significant acute toxicity. Its long term hazards are currently unknown.

History

Perylenes have been used as vat dyes since 1912, but they were not manufactured and sold as pigments until 1957. For artists, they are a replacement for historic colors that were made with berries, and are significantly more lightfast.

Pigment Name

PR101-Red Iron Oxide

Pigment Type

earth, synthetic

Chemical Name

iron oxides (synthetic), iron oxide, silica, alumina, lime, and magnesia or hydrated iron oxide

Chemical Formula

Fe2O2 or Fe2O3 x H2O

Properties

Red iron oxide varies in hue and transparency, depending on hydration and slight impurities. Indian Red is a slightly duller, deep brick hue with a bluish undertone. It is very dense and opaque, with excellent tinting strength and covering power. It is dependable when mixing with all other permanent pigments and yields good flesh tints when mixed with Zinc White. It is the synthetic version of PR102, which is a pigment made from earth reds, or natural red iron oxides, and the names applied to PR101 and PR102 often overlap. The synthetic red iron oxides have mostly replaced natural red iron oxides and are brighter, stronger, finer, and more permanent. Indian Red is the highest grade bluish shade. Light Red, English Red, and Venetian Red are yellowish shades. Mars Violet is a dull and subdued bluish or purplish oxide.

Permanence

Red iron oxide is very lightfast with excellent permanence.

Toxicity

Red iron oxide has no significant hazards.

History

Natural red iron oxide comes from the mineral ore hematite, called bloodstone by the ancient Greeks from the word hema, meaning blood. It is one of the oldest pigments, has been used by every major civilization, and was an important mineral for medieval alchemists. It was not widely used in artists' materials until the 17th century and was not produced in large quantities until the 18th century.