Grumbacher Academy Acrylic - Naples Yellow, 75 ml tube

Pigment Information

This color contains the following pigments:

PR188 -Naphthol Red

PW6-Titanium White

PY65-Hansa Yellow

PBk9-Ivory Black

Pigment Name

PR188 -Naphthol Red

Pigment Type

organic monoazo

Chemical Formula

C33H24Cl2N2O6

Properties

This Naphthol Red is yellowish, with a high tinting strength and average drying time. It produces warmer shades and tints.

Permanence

This Naphthol Red has excellent lightfastness, though it is generally not considered adequate for exterior use.

Toxicity

Naphthol Reds are not considered toxic. They may cause eye, skin, or respiratory irritation. Contact with dry pigment should be avoided.

History

Naphthol pigments are actually dyes that are "laked" to form pigments. First developed by the German chemical company Hoechst A.G. before World War I, their use in artist paints began in the 1920s.

Pigment Name

PW6-Titanium White

Pigment Type

inorganic

Chemical Name

titanium dioxide

Chemical Formula

TiO2

Properties

Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.

Permanence

Titanium White has excellent permanence and lightfastness.

Toxicity

Titanium dioxide is highly stable and is regarded as non-toxic.

History

Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.

Pigment Name

PY65-Hansa Yellow

Pigment Type

monoazo

Chemical Formula

C18H18N4O6

Properties

This Hansa Yellow ranges from reddish yellow to greenish yellow with temperature shifts from cool to warm hues. It has good tinting strength and average to slow drying time.

Permanence

This Hansa Yellow has excellent lightfastness, particularly in the darker shades.

Toxicity

Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.

Pigment Name

PBk9-Ivory Black

Pigment Type

charred animal bone

Chemical Name

carbon + calcium phosphate

Chemical Formula

C + Ca3(PO4)2 or C x CaPO4

Properties

Ivory Black is a cool, semi-transparent blue-black with a slight brownish undertone and average tinting strength. It mixes well with any color, and creates a range of dull greens when mixed with yellow. It has good properties for use in oil, can be slow to dry in oil form, and should never be used in underpainting or frescoing. Ivory Black is denser than Lamp Black.

Permanence

Ivory Black is very lightfast and has good permanence, though it is considered the least permanent of the major black pigments.

Toxicity

Ivory Black has no significant hazards.

History

Ivory Black is a carbon based black first named as Elephantium, and described in the 4th century BCE as produced by heating ivory scraps in clay pots to reduce the ivory or bone to charcoal. The deviation in names is because the more expensive varieties of this pigment were made by burning ivory, and the less expensive ones by burning animal bone. In the 19th century, the name Ivory Black was finally permitted to be applied to Carbon Black pigments made from bone. True Ivory Black is rare in modern times due to the protection of ivory, and the synthetic variety produced today was discovered in 1929. Bone Black is produced as an industrial pigment.