Grumbacher Academy Acrylic - Cadmium Red Medium Hue, 200 ml tube

Pigment Information

This color contains the following pigments:

PR170-Naphthol Red

PY83-Diarylide Yellow 83

PY74-Hansa Yellow

PW6-Titanium White

PBk9-Ivory Black

Pigment Name

PR170-Naphthol Red

Pigment Type

organic, naphthol AS

Chemical Formula

C26H22N4O4

Properties

Pigment PR170 is a bright deep red with bluish undertones. It has an average drying time. It has two crystaline forms that differ significantly in opacity. The more transparent form (F5RK) tends to be more bluish and is less lightfast.

Permanence

The lightfastness and weatherfastness of Pigment PR170 varies, depending on the application and the crystaline form. The opaque form (F3RK) has very good lightfastness, and is more weather resistant. The transparent form (F5RK) has lightfastness that is considered acceptable in pure applications, but it fades more in tints. Neither form is considered suitable for exterior use.

Toxicity

Naphthol Reds are not considered toxic. They may cause eye, skin, or respiratory irritation. Contact with dry pigment should be avoided.

History

Naphthol pigments are actually dyes that are "laked" to form pigments. First developed by the German chemical company Hoechst A.G. before World War I, their use in artist paints began in the 1920s. Pigment Red PR170 is a Naphthol AS pigment, chemically related to the diarylide yellow pigments. The Naphthol AS pigments comprise a range of reds. They are used in plastics, textiles, and printing inks.

Pigment Name

PY83-Diarylide Yellow 83

Pigment Type

organic, disazo

Chemical Formula

C36H32Cl4N6O8

Properties

Diarylide Yellow is a semi-opaque, moderately staining, intense deep reddish yellow pigment with good tinting strength.

Permanence

Diarylide Yellow 83 has very good lightfastness and permanence. However, it can fade in tints, so some artists do not consider it suitable as an artists' color. Many other diarylide yellow pigments are reported to have fair to poor lightfastness, and some are completely fugitive. Diarylide Yellow 83 is reputed to be one of the most permanent of the entire group.

Toxicity

Diarylide Yellow has no significant acute hazards, but chronic hazards have not been well studied.

History

Diarylide Yellow comes from a family of azo pigments called Diarylide. These yellow hued pigments were developed around 1940 and are very important in printing inks.

Pigment Name

PY74-Hansa Yellow

Pigment Type

monoazo

Chemical Formula

C18H18N4O6

Properties

Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.

Permanence

This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.

Toxicity

Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.

Pigment Name

PW6-Titanium White

Pigment Type

inorganic

Chemical Name

titanium dioxide

Chemical Formula

TiO2

Properties

Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.

Permanence

Titanium White has excellent permanence and lightfastness.

Toxicity

Titanium dioxide is highly stable and is regarded as non-toxic.

History

Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.

Pigment Name

PBk9-Ivory Black

Pigment Type

charred animal bone

Chemical Name

carbon + calcium phosphate

Chemical Formula

C + Ca3(PO4)2 or C x CaPO4

Properties

Ivory Black is a cool, semi-transparent blue-black with a slight brownish undertone and average tinting strength. It mixes well with any color, and creates a range of dull greens when mixed with yellow. It has good properties for use in oil, can be slow to dry in oil form, and should never be used in underpainting or frescoing. Ivory Black is denser than Lamp Black.

Permanence

Ivory Black is very lightfast and has good permanence, though it is considered the least permanent of the major black pigments.

Toxicity

Ivory Black has no significant hazards.

History

Ivory Black is a carbon based black first named as Elephantium, and described in the 4th century BCE as produced by heating ivory scraps in clay pots to reduce the ivory or bone to charcoal. The deviation in names is because the more expensive varieties of this pigment were made by burning ivory, and the less expensive ones by burning animal bone. In the 19th century, the name Ivory Black was finally permitted to be applied to Carbon Black pigments made from bone. True Ivory Black is rare in modern times due to the protection of ivory, and the synthetic variety produced today was discovered in 1929. Bone Black is produced as an industrial pigment.