PB27-Prussian Blue
PY74-Hansa Yellow
PY42-Yellow Iron Oxide
PB27-Prussian Blue
inorganic
ferric ferrocyanide/iron(III)-hexacyanoferrate(II)
Fe7(CN)18(H2O)x or C6FeN6H4N
Prussian Blue is a semi-transparent, deep cyan-blue with a greenish undertone and a very high tinting strength unequaled by most pigments. It is similar to Phthalo Blue unless mixed with white, when it gives up intensity and becomes smoky. It can behave erratically and less reliably in oil and watercolor form depending on its manufacture. For permanent painting Phthalo Blue is considered a more reliable choice.
Prussian Blue is lightfast and permanent in all techniques except for fresco. When mixed with Zinc White in watercolor or tempera form, it fades upon exposure to light and completely regains its chromatic strength in the dark. Modern manufacturing techniques have made this tendency less of an issue in recent years
Prussian Blue is moderately toxic if ingested. It will emit toxic hydrogen cyanide gas if heated, exposed to ultraviolet radiation, or treated with acid.
"The first of the modern pigments," Prussian Blue is the first artificial pigment with a known history. It was discovered by accident in 1704 by the Berlin color maker Heinrich Diesbach, who was trying to create a pigment with a red hue by mixing iron sulfate and potash. The potash Diesbach purchased from a local laboratory had been contaminated by animal oil and blood during previous experimentation. The resulting mixture yielded a very pale red that changed to purple and then deep blue when he tried to concentrate it. Since previous blue pigments came from lapis lazuli, an expensive stone, Diesbach’s discovery was extremely important for artists of the time.
PY74-Hansa Yellow
monoazo
C18H18N4O6
Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.
This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.
Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.
Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.
PY42-Yellow Iron Oxide
iron(III)-oxide, hydrated
Fe2O3 • H2O
Yellow Ochre provides artists with earthtones from cream to brown. It has good hiding power, produces a quick drying paint, and can be safely mixed with other pigments. Its transparency varies widely from opaque shades to more transparent ones, which are valued for their use as glazes. If gypsum is present, Yellow Ochre is not suitable for frescoing. (See Brown Ochre, PY43.) PY42 is made from synthetic iron oxides. PY43 is made from natural iron oxide.
Yellow Ochre has excellent permanence because ochres are some of the most permanent pigments available.
Yellow Ochre is non-toxic unless it contains manganese.
Ochre comes from the Greek word ochros, meaning pale yellow. It was one of the first pigments to be used by human beings, and evidence of its use has been found at 300,000 year old sites in France and the former Czechoslovakia.
UPC Code: 655802103192
ASIN #: B07SK9J7JB