Sennelier French Artists' Watercolor - Indigo, Half Pan

Pigment Information

This color contains the following pigments:

PBk7-Lamp Black

PB15:1-Phthalo Blue

PB60-Indanthrene Blue

Pigment Name

PBk7-Lamp Black

Pigment Type

inorganic

Chemical Name

carbon

Chemical Formula

C

Properties

Lamp black is a very opaque, heavily staining black pigment that does not have much covering or tinting power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures. Natural sources may be brownish or bluish in tone because of impurities. When used in oil paints, it is one of the slowest drying pigments, and should not be used in underpainting or applied in layers underneath other colors.

Permanence

Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.

Toxicity

<p>Carbon itself is not considered hazardous, however other combustion products that are hazardous are often present as impurities when Lamp Black is produced from natural materials. For this reason, commercial preparations of the pigment should be considered slightly toxic. Avoid skin contact and inhalation. Where such impurities are present, Lamp Black is a possible human carcinogen.</p>

History

Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It has been used as a pigment since prehistoric times. It is the black found in Egyptian murals and tomb decorations and was the most popular black for fresco painting until the development of Mars Black.

Pigment Name

PB15:1-Phthalo Blue

Pigment Type

organic

Chemical Name

alpha copper phthalocyanine

Chemical Formula

C32H16CuN8

Properties

Phthalo Blue PB15:1 is a structural variant of Phthalo Blue PB15 that produces more reddish tones.

Permanence

Phthalo Blues are completely lightfast and stable and are permanent for all paint uses. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.

Toxicity

Phthalo Blues have no significant hazards, although those made before 1982 contained some PCBs (polychlorinated biphenyls).

History

Developed by chemists using the trade name Monastral Blue, the organic blue dyestuff now known as Phthalo Blue was presented as a pigment in November 1935 in London. Its discovery was accidental. The dark color was observed in a kettle where a dye was being made from a British dyestuff plant. The demand for such a pigment came from commercial printers who wanted a cyan to replace Prussian Blue.

Pigment Name

PB60-Indanthrene Blue

Pigment Type

organic, vat dyes

Chemical Name

complex, insoluble anthraquinone

Chemical Formula

C28H14N2O4

Properties

Indanthrene Blue is a clear, clean, deep blue organic pigment. It has moderate to high tinting strength and is not as overpowering as Phthalo Blue. Hansa Yellow Deep, Benzimidazolone Orange, and Raw Umber are its best mixing complements.

Permanence

Indanthrene Blue is permanent with excellent lightfastness in both masstone and tints.

Toxicity

Indanthrene Blue varies in its acute toxicity, though toxicity is generally slight.

History

Indanthrene Blue is the oldest vat dye, discovered and patented in 1901 by Rene Bohn. It is considered the first anthraquinone vat dye, a group of dyes characterized by excellent lightfastness. The pigment originates from this dye.