Sennelier French Artists' Watercolor - Forest Green, Half Pan

Pigment Information

This color contains the following pigments:

PBk7-Lamp Black

PG7-Phthalo Green

PY42-Yellow Iron Oxide

Pigment Name

PBk7-Lamp Black

Pigment Type

inorganic

Chemical Name

carbon

Chemical Formula

C

Properties

Lamp black is a very opaque, heavily staining black pigment that does not have much covering or tinting power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures. Natural sources may be brownish or bluish in tone because of impurities. When used in oil paints, it is one of the slowest drying pigments, and should not be used in underpainting or applied in layers underneath other colors.

Permanence

Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.

Toxicity

<p>Carbon itself is not considered hazardous, however other combustion products that are hazardous are often present as impurities when Lamp Black is produced from natural materials. For this reason, commercial preparations of the pigment should be considered slightly toxic. Avoid skin contact and inhalation. Where such impurities are present, Lamp Black is a possible human carcinogen.</p>

History

Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It has been used as a pigment since prehistoric times. It is the black found in Egyptian murals and tomb decorations and was the most popular black for fresco painting until the development of Mars Black.

Pigment Name

PG7-Phthalo Green

Pigment Type

organic

Chemical Name

polychlorinated copper(II) phthalocyanine

Chemical Formula

C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)

Properties

Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules. It has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors. This pigment most closely resembles the discontinued and toxic Verdigris.

Permanence

Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.

Toxicity

Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.

History

This bright blue-green was developed in 1935 and has been in use since 1938.

Pigment Name

PY42-Yellow Iron Oxide

Chemical Name

iron(III)-oxide, hydrated

Chemical Formula

Fe2O3&nbsp;&bull;&nbsp;H2O

Properties

Yellow Ochre provides artists with earthtones from cream to brown. It has good hiding power, produces a quick drying paint, and can be safely mixed with other pigments. Its transparency varies widely from opaque shades to more transparent ones, which are valued for their use as glazes. If gypsum is present, Yellow Ochre is not suitable for frescoing. (See Brown Ochre, PY43.) PY42 is made from synthetic iron oxides. PY43 is made from natural iron oxide.

Permanence

Yellow Ochre has excellent permanence because ochres are some of the most permanent pigments available.

Toxicity

Yellow Ochre is non-toxic unless it contains manganese.

History

Ochre comes from the Greek word ochros, meaning pale yellow. It was one of the first pigments to be used by human beings, and evidence of its use has been found at 300,000 year old sites in France and the former Czechoslovakia.