Daniel Smith Watercolor Stick - Olive Green

Pigment Information

This color contains the following pigments:

PY97-Permanent Yellow

PB29-Ultramarine [Blue]

PBr7-Raw Umber

Pigment Name

PY97-Permanent Yellow

Pigment Type

organic, monoazo

Chemical Formula

C26H27ClN4O8

Properties

Permanent Yellow PY97 ranges from reddish yellow to greenish yellow with temperature shifts from cool to warm hues. It has good tinting strength and average to slow drying time. Similar in shade to Hansa Yellow 1, it offers much better fastness properties and good heat stability.

Permanence

Pigment PY97 has excellent lightfastness, particularly in the darker shades.

Toxicity

No significant acute hazards of PY97 are known, though chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow. Permanent Yellow (PY97) represents a further development of this line, with the aim of producing a yellow pigment that is suitable for exterior use.

Pigment Name

PB29-Ultramarine [Blue]

Pigment Type

inorganic

Chemical Name

complex silicate of sodium and aluminum with sulfur

Chemical Formula

Na8-10Al6Si6O24S2-4 or Na6-8Al6Si6O24S2-4

Properties

Ultramarine is the standard warm blue, a brilliant blue pigment that has the most purple and least green in its undertone. It has a moderate to high tinting strength and a beautiful transparency. Synthetic Ultramarine is not as vivid a blue as natural Ultramarine. Ultramarine dries slowly in oil and tends to produce clean, though granular, washes in watercolor. French Ultramarine mixes well with Alizarin colors in oil and watercolor form to create a range of purples and violets. It can dull when mixed with white in acrylic form, but mixes well with other colors. The shade varies based on manufacturer. Considered a great color for glazes, it is not suitable for frescoing.

Permanence

Ultramarine has excellent permanence, although synthetic Ultramarine is not as permanent as natural Ultramarine. It may discolor if exposed to acid because of its sulfuric content.

Toxicity

Ultramarine has no significant hazards.

History

The name for this pigment comes from the Middle Latin ultra, meaning beyond, and mare, meaning sea, because it was imported from Asia to Europe by sea. It is a prominent component of lapis lazuli and was used on Asian temples starting in the 6th century. It was one of the most expensive pigments in 16th century Europe, worth twice its weight in gold, and so was used sparingly and when commissions were larger. Ultramarine is currently imitated by a process invented in France in 1826 by Jean Baptiste Guimet, making blue affordable to artists and extending the range of colors on their palettes.

Pigment Name

PBr7-Raw Umber

Pigment Type

earth

Chemical Name

hydrated iron oxide

Chemical Formula

α-FeO3+(OH) or Fe2O3 × MnO2

Properties

Raw Umber is a cool, transparent brown ranging from yellowish brown to greenish brown. It has surprisingly good tinting strength, a high level of opacity, mixes well with greens, and is quick drying in oil form. It has excellent color properties and can create a variety of subtle, clear tints when mixed with white. It grays when mixed with blue and white. Raw Umber can tend towards chalkiness in dark mixes in oil form.

Permanence

Raw Umber has excellent permanence.

Toxicity

Raw Umber itself is considered non-toxic. If contaminated by manganese compounds, it may be highly toxic if inhaled and moderately toxic if ingested.

History

This pigment gets its name from the Latin word umbra, meaning shadow or shade. Its full name is listed as terra di ombra, meaning earth of shadow/shade, due to its original extraction from the area of Umbria, Italy. It has been used as a pigment since prehistoric times. Currently, the finest umber comes from Cyprus.