This color contains the following pigments:
Red Iron Oxide
hydrated iron oxide
α-FeO3+(OH) or Fe2O3
Raw Sienna is a moderately dull deep earth yellow with medium tinting strength and excellent transparency. It is one of the basic permanent artists' pigments and is made from a form of limonite clay whose yellow-brown color results from ferric oxides. Raw Sienna is preferable to Yellow Ochre for creating flesh tones, due to its higher subtlety of color when mixed with white. It creates a bright Ochre when mixed with Cadmium Yellow and creates greens and grays when mixed with Ultramarine. Raw Sienna dries quickly.
Raw Sienna has good permanence.
Raw Sienna has no significant hazards.
Raw Sienna has been used as a pigment since prehistoric times, although its current name came about during the Renaissance. It comes from the city of Siena, in Italy, and is short for terra di Siena, meaning earth of Siena. Sienna was famous for the mining and production of earth pigments from the Renaissance until World War II. Due to the depletion of clay deposits in Tuscany, Italian siennas now come from other areas, including Sicily and Sardinia.
Red Iron Oxide
iron oxides (synthetic), iron oxide, silica, alumina, lime, and magnesia or hydrated iron oxide
Fe2O2 or Fe2O3 • H2O
Red iron oxide varies in hue and transparency, depending on hydration and slight impurities. Indian Red is a slightly duller, deep brick hue with a bluish undertone. It is very dense and opaque, with excellent tinting strength and covering power. It is dependable when mixing with all other permanent pigments and yields good flesh tints when mixed with Zinc White. It is the synthetic version of PR102, which is a pigment made from earth reds, or natural red iron oxides, and the names applied to PR101 and PR102 often overlap. The synthetic red iron oxides have mostly replaced natural red iron oxides and are brighter, stronger, finer, and more permanent. Indian Red is the highest grade bluish shade. Light Red, English Red, and Venetian Red are yellowish shades. Mars Violet is a dull and subdued bluish or purplish oxide.
Red iron oxide is very lightfast with excellent permanence.
Red iron oxide has no significant hazards.
Natural red iron oxide comes from the mineral ore hematite, called bloodstone by the ancient Greeks from the word hema, meaning blood. It is one of the oldest pigments, has been used by every major civilization, and was an important mineral for medieval alchemists. It was not widely used in artists' materials until the 17th century and was not produced in large quantities until the 18th century.