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PY3—Hansa Yellow 10G

Pigment Type

organic, monoazo

Chemical Name

n/a

Chemical Formula

C₁₆H₁₂CL₂N₄O₂

Properties

This Hansa yellow is a transparent yellow. It has great brightness and tinting strength and its drying time ranges from average to slow.

Hansa Yellow makes more intense tints and cleaner secondaries than Cadmium Yellows, especially when mixed with other organic or modern colors like Phthalo Blue and Green. Because they are more transparent, they have great value as glazing colors.

Permanence

This Hansa Yellow has fair to good permanence, particularly in the lighter shades.

Toxicity

Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.

Alternate Names

Arylamide Yellow, Arylide, Arylide Yellow, Azo, Brilliant Yellow, Monoazo, Monolite Yellow, Permanent Yellow.

PY97—Permanent Yellow

Pigment Type

organic, monoazo

Chemical Name

n/a

Chemical Formula

C₂₆H₂₇ClN₄O₈

Properties

Permanent Yellow PY97 ranges from reddish yellow to greenish yellow with temperature shifts from cool to warm hues. It has good tinting strength and average to slow drying time. Similar in shade to Hansa Yellow 1, it offers much better fastness properties and good heat stability.

Permanence

Pigment PY97 has excellent lightfastness, particularly in the darker shades.

Toxicity

No significant acute hazards of PY97 are known, though chronic hazards have not been well studied.

History

Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow. Permanent Yellow (PY97) represents a further development of this line, with the aim of producing a yellow pigment that is suitable for exterior use.

Alternate Names

Arylide, Arylide Yellow, Azo, Brilliant Yellow, Monoazo, Monolite Yellow, Hansa Yellow.

PW6—Titanium White

Pigment Type

inorganic

Chemical Name

titanium dioxide

Chemical Formula

TiO₂

Properties

Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.

Permanence

Titanium White has excellent permanence and lightfastness.

Toxicity

Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.

History

Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.

Alternate Names

None.