Holbein Artists' Watercolor - Sap Green, Half Pan

Item #:00322-7090
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Sap Green
Sap Green

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AP Non-Toxic.

Product Details

Color:
Sap Green
No.
PN547
Series:
B

Pigment Information

This color contains the following pigments:

PG8-Hooker’s Green

PY17-Permanent Yellow

PG36-Phthalo Green


Pigment Name

PG8-Hooker’s Green

Pigment Type

mix of organic pigments

Chemical Formula

C30H18FeN3O6Na

Properties

Hooker’s Green is a bright olive-green often sold in a yellowish shade and a bluish shade. Its transparency can range from dull and dark to bright and light because lightness and chroma vary based on manufacturer. Modern varieties have a rich, dark tone that provides a great range when mixing. Hooker’s Green is particularly good for landscape painting when a larger range of foliage is required. Dioxazine Violet is the best mixing compliment in watercolor form.

Permanence

The permanence and lightfastness of Hooker’s Green varies by brand. As a composite pigment historically mixed from Prussian Blue and Gamboge, its permanence is only fair. Modern replacements for Hooker's Green tend to be mixed with components that have more permanence, such as Phthalocyanine Green, Burnt Umber, and sometimes Hansa or Cobalt Yellow.

Toxicity

Hooker’s Green can be hazardous, but the toxicity level depends on the specific pigments used by each individual manufacturer or brand.

History

This pigment was originally an unreliable mix of Prussian or Iron Blue and Gamboge. Later, it became a more reliable mix of Cadmium Yellow and Phthalo Blue or Green. It was a staple green for 19th century landscape and botanical painters. Most modern Hooker’s Green paints are yellow greens with a hue angle around 140, or a mix of Phthalo Green and Burnt Umber.


Pigment Name

PY17-Permanent Yellow

Pigment Type

organic, disazo

Chemical Name

Benzidine Yellow GG

Chemical Formula

Properties

Pigment Yellow 17 is a somewhat greenish yellow that has very high tinting strength and good resistance to solvents.

Permanence

Pigment Yellow 17 has good lightfastness if prepared using the proper procedures. Because procedures for preparing PY17 vary, artists may want to conduct their own lightfastness tests to verify that the manufacturer has selected quality pigment.

Toxicity

Benzidine dyes are not bioavailable. Although benzidine-based dyes can be reduced to their amine precursors in vivo, creating a compound that is carcinogenic, benzidine dyes are believed to be so insoluble in water that they are unlikely to be absorbed in

History

This Benzidine Yellow dye was first reported by Esitelty in 1949. Initiailly, it was reported to be less lightfast than yellow monoazo pigments, which limited its usefulness. A method for making Pigment Yellow 17 more permanent was patented in 1972 (United States Patent 3785843), and the improved dye became known as Permanent Yellow. Permanent Yellow 17 is widely used in printing inks, textile dyes, paints, plastics, and coatings.


Pigment Name

PG36-Phthalo Green

Pigment Type

organic

Chemical Name

polybromopolychlorinated copper(II) phthalocyanine

Chemical Formula

C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)

Properties

Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules.  Pigment PG36 differs from PG7 in that a portion of the chlorine atoms are replaced with bromine atoms, which are reactively similar, but cause a yellow shift that is especially noticeable in mixtures. Phthalo Green has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors.  This pigment most closely resembles the discontinued and toxic Verdigris.

Permanence

Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.

Toxicity

Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.

History

This bright blue-green was developed in 1935 and has been in use since 1938.


Safety Data Sheet

UPC Code: 4900669025474

ASIN #: B014IRIQ2O