Holbein Artists' Watercolor - Payne's Gray, Half Pan

Item #:00322-2560
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Payne's Gray
Payne's Gray

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AP Non-Toxic.

Product Details

Color:
Payne's Gray
No.
PN621
Series:
A

Pigment Information

This color contains the following pigments:

PBk7-Lamp Black

PB29-Ultramarine [Blue]

PR83-Alizarin Crimson

PB27-Antwerp Blue


Pigment Name

PBk7-Lamp Black

Pigment Type

inorganic

Chemical Name

carbon

Chemical Formula

C

Properties

Lamp black is a very opaque, heavily staining black pigment that does not have much covering or tinting power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures. Natural sources may be brownish or bluish in tone because of impurities. When used in oil paints, it is one of the slowest drying pigments, and should not be used in underpainting or applied in layers underneath other colors.

Permanence

Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.

Toxicity

Carbon itself is not considered hazardous, however other combustion products that are hazardous are often present as impurities when Lamp Black is produced from natural materials. For this reason, commercial preparations of the pigment should be considere

History

Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It has been used as a pigment since prehistoric times. It is the black found in Egyptian murals and tomb decorations and was the most popular black for fresco painting until the development of Mars Black.


Pigment Name

PB29-Ultramarine [Blue]

Pigment Type

inorganic

Chemical Name

complex silicate of sodium and aluminum with sulfur

Chemical Formula

Na8-10Al6Si6O24S2-4 or Na6-8Al6Si6O24S2-4

Properties

Ultramarine is the standard warm blue, a brilliant blue pigment that has the most purple and least green in its undertone. It has a moderate to high tinting strength and a beautiful transparency. Synthetic Ultramarine is not as vivid a blue as natural Ultramarine. Ultramarine dries slowly in oil and tends to produce clean, though granular, washes in watercolor. French Ultramarine mixes well with Alizarin colors in oil and watercolor form to create a range of purples and violets. It can dull when mixed with white in acrylic form, but mixes well with other colors. The shade varies based on manufacturer. Considered a great color for glazes, it is not suitable for frescoing.

Permanence

Ultramarine has excellent permanence, although synthetic Ultramarine is not as permanent as natural Ultramarine. It may discolor if exposed to acid because of its sulfuric content.

Toxicity

Ultramarine has no significant hazards.

History

The name for this pigment comes from the Middle Latin ultra, meaning beyond, and mare, meaning sea, because it was imported from Asia to Europe by sea. It is a prominent component of lapis lazuli and was used on Asian temples starting in the 6th century. It was one of the most expensive pigments in 16th century Europe, worth twice its weight in gold, and so was used sparingly and when commissions were larger. Ultramarine is currently imitated by a process invented in France in 1826 by Jean Baptiste Guimet, making blue affordable to artists and extending the range of colors on their palettes.


Pigment Name

PR83-Alizarin Crimson

Pigment Type

organic

Chemical Name

1,2-dihydroxyantraquinone

Chemical Formula

C14H8O4

Properties

Alizarin Crimson, the traditional cool counterpart to Cadmium Red, is a clear ruby-red with a maroon masstone and a bluish undertone. It is the artist's principal deep red pigment, is transparent, and has good tinting strength. It creates bright rosy pinks when mixed with white, a range of purples and violets when mixed with strong blues, can be slow drying when used with oils, and is compatible with all other pigments. Permanent Alizarin Crimson mixes well with Ultramarine in acrylic and watercolor form. Permanent Rose and Quinacridone Rose are possible alternatives on a watercolor palette. Alizarin Crimson is a popular glazing color.

Permanence

Alizarin Crimson is considered fugitive or marginally lightfast, and the appropriateness of its use in the modern artist palette is a subject of debate. There are many concerns regarding its permanence, particularly when mixed with ochre, sienna, and umber, or when used thinly. It is the least permanent red commonly used by today’s artists. Modern synthetic preparations of Alizarin Crimson have better permanence and lightfastness that the original natural pigment, which was extracted from the madder plant. Quinacridone pigments have been used to create a modern hue that closely matches the original hue, but many artists object that the transparency and handling characteristics are not the same as for the original.

Toxicity

Alizarin Crimson can be slightly toxic if it comes into contact with skin and may cause some allergies. There is no significant acute toxicity.

History

The word alizarin comes from the Arabic word al-usara, meaning juice. The base ingredient of this pigment is the Madder plant (Rubia Tinctorum). It was used for dyes and inks among craftsmen in Ancient Persia, India, and Egypt as early as 1500 BC In 1804, George Field, an English dye maker, developed Madder Lake by binding madder to alum, a white powder. The German chemists Carl Grabe and Carl Liebermann produced the first synthetic variety of this pigment, most commonly known as Alizarin Crimson, in 1868. They used anthracene, which greatly improved the lightfastness. The Colour Index International designation PR83:1 has been used to identify this synthetic laked pigment.


Pigment Name

PB27-Antwerp Blue

Pigment Type

inorganic

Chemical Name

ferric ammonium ferrocyanide

Chemical Formula

C18Fe7N18

Properties

Antwerp Blue is a slightly warm and less saturated blue with good transparency and undertone clarity. It is a pale variety of Prussian Blue with 75% inert pigment. It has similar properties to pure Prussian Blue, but its overall performance is inferior.

Permanence

Antwerp Blue can fluctuate, fading in the light and recovering in the dark. In watercolor form, it fades when mixed with white pigment or extender. Although it has reasonably good lightfastness and permanence, it is not considered ideal for permanent painting.

Toxicity

Antwerp Blue is mildly toxic by ingestion, but is considered safe for external use. In the United States, ferric ferrocyanide is permitted as a coloring ingredient for externally applied cosmetics, but not for lipsticks or internal use. If the pigment is

History

Antwerp Blue was developed through experimentation with Prussian Blue.


Safety Data Sheet

UPC Code: 4900669026211

ASIN #: B014IRL9CI