Color Swatch created using heavy to light application and was applied on 100 lb (163 gsm) drawing paper material.
This color contains the following pigments:
PBr7—Raw Sienna
Pigment Type
earth
Chemical Name
hydrated iron oxide
Chemical Formula
α-FeO3+(OH) or Fe2O3
Properties
Raw Sienna is a moderately dull deep earth yellow with medium tinting strength and excellent transparency. It is one of the basic permanent artists' pigments and is made from a form of limonite clay whose yellow-brown color results from ferric oxides. Raw Sienna is preferable to Yellow Ochre for creating flesh tones, due to its higher subtlety of color when mixed with white. It creates a bright Ochre when mixed with Cadmium Yellow and creates greens and grays when mixed with Ultramarine. Raw Sienna dries quickly.
Permanence
Raw Sienna has good permanence.
Toxicity
Raw Sienna has no significant hazards.
History
Raw Sienna has been used as a pigment since prehistoric times, although its current name came about during the Renaissance. It comes from the city of Siena, in Italy, and is short for terra di Siena, meaning earth of Siena. Sienna was famous for the mining and production of earth pigments from the Renaissance until World War II. Due to the depletion of clay deposits in Tuscany, Italian siennas now come from other areas, including Sicily and Sardinia.
Alternate Names
Italian Earth, Natural Brown Iron Oxide, Sienna.
PY74—Hansa Yellow
Pigment Type
monoazo
Chemical Name
n/a
Chemical Formula
C18H18N4O6
Properties
Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.
Permanence
This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.
Toxicity
Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.
History
Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.
Alternate Names
Arylide, Arylide Yellow, Azo, Brilliant Yellow, Monoazo, Monolite Yellow, Permanent Yellow.
PW6—Titanium White
Pigment Type
inorganic
Chemical Name
titanium dioxide
Chemical Formula
TiO2
Properties
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Permanence
Titanium White has excellent permanence and lightfastness.
Toxicity
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
History
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Alternate Names
None.
