Color Swatch created using heavy to light application and was applied on 100 lb (163 gsm) drawing paper material.
This color contains the following pigments:
PY74—Hansa Yellow
Pigment Type
monoazo
Chemical Name
n/a
Chemical Formula
C18H18N4O6
Properties
Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.
Permanence
This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.
Toxicity
Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.
History
Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.
Alternate Names
Arylide, Arylide Yellow, Azo, Brilliant Yellow, Monoazo, Monolite Yellow, Permanent Yellow.
PBk7—Lamp Black
Pigment Type
inorganic
Chemical Name
carbon
Chemical Formula
C
Properties
Lamp black is a very opaque, heavily staining black pigment that does not have much covering or tinting power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures. Natural sources may be brownish or bluish in tone because of impurities. When used in oil paints, it is one of the slowest drying pigments, and should not be used in underpainting or applied in layers underneath other colors.
Permanence
Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.
Toxicity
Carbon itself is not considered hazardous, however other combustion products that are hazardous are often present as impurities when Lamp Black is produced from natural materials. For this reason, commercial preparations of the pigment should be considered slightly toxic. Avoid skin contact and inhalation. Where such impurities are present, Lamp Black is a possible human carcinogen.
History
Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It has been used as a pigment since prehistoric times. It is the black found in Egyptian murals and tomb decorations and was the most popular black for fresco painting until the development of Mars Black.
Alternate Names
Carbon Black, Channel Black, Furnace Black, Oil Black, Vegetable Black. Flame Black is an impure version of Lamp Black. An alternate spelling is Lampblack, in which the first syllable is stressed and the two words are elided to form a closed compound.
PG7—Phthalo Green
Pigment Type
organic
Chemical Name
polychlorinated copper(II) phthalocyanine
Chemical Formula
C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)
Properties
Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules. It has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors. This pigment most closely resembles the discontinued and toxic Verdigris.
Permanence
Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.
Toxicity
Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.
History
This bright blue-green was developed in 1935 and has been in use since 1938.
Alternate Names
Bocour Green, Cyan Green, Intense Green, Monastral Green, Phthalocyanine Green, Rembrandt Green, Thalo Green, Winsor Green.
PG17—Chromium Oxide Green
Pigment Type
inorganic
Chemical Name
chromium oxide
Chemical Formula
Cr2O3
Properties
Chromium Oxide Green is a dull, dense, willow or pale green color that is completely opaque. It has an average drying time and a low tinting strength. It is fairly flexible in oil form and is suitable for all purposes and mediums. This pigment is less versatile in mixtures than Viridian and Phthalocyanine Green, but mixes well with other colors without overpowering them.
Permanence
Chromium Oxide Green has excellent permanence, even at high temperatures.
Toxicity
Chromium Oxide Green is slightly toxic. Evidence of Chromium(III) carcinogenicity is inconclusive. Chromium(III) salts appear in greenish pigments such as PG17. Chromium(VI) salts, which appear in yellowish pigments, have been proven to cause cancer.
History
Louis-Nicolas Vauquelin discovered the element chromium in lead chromate in 1797. It began to be used as an enamel and ceramic color in 1809, but it had limited use as a pigment until 1862, because of its cost. It is the most commonly used green for military camouflage because it appears the same shade as living foliage under infrared light.
Alternate Names
Chrome Oxide Green, Olive Green, Permanent Green. Varieties of Chromium Oxide Green include Arnaudon's Green, Dingler's Green, Plessy's Green, and Schnitzer's Green.
PO67—Pyrazoloquinazolone Orange
Pigment Type
organic, monoazo
Chemical Name
pyrazolo-quinazolone orange
Chemical Formula
n/a
Properties
Pyrazolo-Quinazolone Orange is an opaque orange pigment which has excellent dispersal and good coverage.
Permanence
Pyrazolo-Quinazolone Orange is extremely lightfast.
Toxicity
n/a
History
n/a
Alternate Names
Sico Fast Orange, Paliotol Orange
