Color Swatch created using heavy to light application and was applied on 100 lb (163 gsm) drawing paper material.
This color contains the following pigments:
PY1—Hansa Yellow G
Pigment Type
organic, monoazo
Chemical Name
n/a
Chemical Formula
C17H16N4O4
Properties
This Hansa yellow is a transparent yellow. It has great brightness and tinting strength and its drying time ranges from average to slow.
Hansa Yellow makes more intense tints and cleaner secondaries than Cadmium Yellows, especially when mixed with other organic or modern colors like Phthalo Blue and Green. Because they are more transparent, they have great value as glazing colors.
Permanence
Hansa Yellow G has good permanence and lightfastness, particularly in the lighter shades.
Toxicity
Hansa Yellow pigments have no significant acute hazards, though chronic hazards have not been well studied.
History
Hansa Yellows were first made in Germany just before World War I from a series of synthetic dyestuffs called Pigment Yellow. Hansa Yellow G, introduced in 1910, was the first of these products to be commercialized. Hansa Yellow G was the standard yellow for printing inks until late in the 20th century, when stronger diarylide yellows began to replace it. It is still used a great deal in packaging, and for air drying paints.
Alternate Names
Light Fast Yellow G, Pigment Yellow G, Arylide, Arylide Yellow, Azo Yellow, Brilliant Yellow, Monoazo Yellow, Monolite Yellow, Permanent Yellow.
PW6—Titanium White
Pigment Type
inorganic
Chemical Name
titanium dioxide
Chemical Formula
TiO2
Properties
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Permanence
Titanium White has excellent permanence and lightfastness.
Toxicity
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
History
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Alternate Names
None.
PBk9—Ivory Black
Pigment Type
charred animal bone
Chemical Name
carbon + calcium phosphate
Chemical Formula
C + Ca3(PO4)2 or C × CaPO4
Properties
Ivory Black is a cool, semi-transparent blue-black with a slight brownish undertone and average tinting strength. It mixes well with any color, and creates a range of dull greens when mixed with yellow. It has good properties for use in oil, can be slow to dry in oil form, and should never be used in underpainting or frescoing. Ivory Black is denser than Lamp Black.
Permanence
Ivory Black is very lightfast and has good permanence, though it is considered the least permanent of the major black pigments.
Toxicity
Ivory Black has no significant hazards.
History
Ivory Black is a carbon based black first named as Elephantium, and described in the 4th century BCE as produced by heating ivory scraps in clay pots to reduce the ivory or bone to charcoal. The deviation in names is because the more expensive varieties of this pigment were made by burning ivory, and the less expensive ones by burning animal bone. In the 19th century, the name Ivory Black was finally permitted to be applied to Carbon Black pigments made from bone. True Ivory Black is rare in modern times due to the protection of ivory, and the synthetic variety produced today was discovered in 1929. Bone Black is produced as an industrial pigment.
Alternate Names
Animal Black, Blue Black, Bone Black. Paris Black is an inferior grade of Ivory Black. Incorrectly labeled as Frankfort Black.
PBk8—Vine Black
Pigment Type
inorganic
Chemical Name
carbon
Chemical Formula
C
Properties
Black is a semi-transparent, slightly textured blue-black pigment with excellent hiding power. It has a finer grain than other black pigments, so it spreads better in watercolor. However, it is inferior in intensity, tinting strength, and chemical purity to the major black pigments.
Permanence
Vine Black has superior permanence and lightfastness because carbon absorbs light well.
Toxicity
Vine Black has no significant hazards.
History
Vine Black is a carbon based black traditionally produced by charring desiccated grape vines, stems, and wood from willow trees. These processes have been used since antiquity, though a superior artificial variety was developed in the United States in 1864 to make a black appropriate for watercolors.
Alternate Names
Blue Black, Charcoal Black, Coke Black, Cork Black, Drop Black, Frankfort Black, German Black, Grape Black, Kernel Black, Marc Black, Mineral Black, Peach Black, Spanish Black, Vegetable Black, Yeast Black. Blue Black has also been used to describe Ivory Black.
