Color Swatch created using heavy application/diluted application and was applied on cold press watercolor paper (150 lb) material.
This color contains the following pigments:
PBr25—Benzimidazolone Brown
Pigment Type
organic, monoazo benzimidazolone
Chemical Name
n/a
Chemical Formula
n/a
Properties
Benzimidazolone Brown is a transparent brown pigment that is heavily staining and dark valued but has moderately low tinting strength. According to its manufacturer Clariant, “It is a dark brown, very transparent benzimidazolone pigment with excellent light, weather, and solvent fastness properties plus high heat stability. Recommended for paste inks, solvent and water based packaging gravure, and flexographic printing inks.” Benzimidazolone Brown has been used in watercolor painting, where transparent brown colors have traditionally been mixed from other pigments.
Permanence
Benzimidazolone Brown has excellent lightfastness and weather resistance.
Toxicity
n/a
History
Benzimidazolone pigments were developed and patented by Hoechst in 1960, and have gradually come into use as artist pigments.
Alternate Names
Renol Brown, Viscofil Brown, Microdis Brown, Hostaperm Brown HFR.
PY17—Permanent Yellow
Pigment Type
organic, disazo
Chemical Name
Benzidine Yellow GG
Chemical Formula
n/a
Properties
Pigment Yellow 17 is a somewhat greenish yellow that has very high tinting strength and good resistance to solvents.
Permanence
Pigment Yellow 17 has good lightfastness if prepared using the proper procedures. Because procedures for preparing PY17 vary, artists may want to conduct their own lightfastness tests to verify that the manufacturer has selected quality pigment.
Toxicity
Benzidine dyes are not bioavailable. Although benzidine-based dyes can be reduced to their amine precursors in vivo, creating a compound that is carcinogenic, benzidine dyes are believed to be so insoluble in water that they are unlikely to be absorbed in a quantity sufficient to be carcinogenic.
History
This Benzidine Yellow dye was first reported by Esitelty in 1949. Initiailly, it was reported to be less lightfast than yellow monoazo pigments, which limited its usefulness. A method for making Pigment Yellow 17 more permanent was patented in 1972 (United States Patent 3785843), and the improved dye became known as Permanent Yellow. Permanent Yellow 17 is widely used in printing inks, textile dyes, paints, plastics, and coatings.
Alternate Names
Benzidine Yellow GG, Diarylide Yellow 17
PG36—Phthalo Green
Pigment Type
organic
Chemical Name
polybromopolychlorinated copper(II) phthalocyanine
Chemical Formula
C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)
Properties
Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules. Pigment PG36 differs from PG7 in that a portion of the chlorine atoms are replaced with bromine atoms, which are reactively similar, but cause a yellow shift that is especially noticeable in mixtures. Phthalo Green has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors. This pigment most closely resembles the discontinued and toxic Verdigris.
Permanence
Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.
Toxicity
Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.
History
This bright blue-green was developed in 1935 and has been in use since 1938.
Alternate Names
Bocour Green, Cyan Green, Intense Green, Monastral Green, Phthalocyanine Green, Rembrandt Green, Thalo Green, Winsor Green.
