Color Swatch created using heavy application/medium application/50% tint and was applied on acrylic primed canvas (7 oz) material.
This color contains the following pigments:
PW6—Titanium White
Pigment Type
inorganic
Chemical Name
titanium dioxide
Chemical Formula
TiO2
Properties
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Permanence
Titanium White has excellent permanence and lightfastness.
Toxicity
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
History
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Alternate Names
None.
PY74—Hansa Yellow
Pigment Type
monoazo
Chemical Name
n/a
Chemical Formula
C18H18N4O6
Properties
Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.
Permanence
This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.
Toxicity
Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.
History
Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.
Alternate Names
Arylide, Arylide Yellow, Azo, Brilliant Yellow, Monoazo, Monolite Yellow, Permanent Yellow.
PG7—Phthalo Green
Pigment Type
organic
Chemical Name
polychlorinated copper(II) phthalocyanine
Chemical Formula
C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)
Properties
Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules. It has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors. This pigment most closely resembles the discontinued and toxic Verdigris.
Permanence
Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.
Toxicity
Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.
History
This bright blue-green was developed in 1935 and has been in use since 1938.
Alternate Names
Bocour Green, Cyan Green, Intense Green, Monastral Green, Phthalocyanine Green, Rembrandt Green, Thalo Green, Winsor Green.
