Color Swatch created using heavy application/medium application/50% tint and was applied on acrylic primed canvas (7 oz) material.
This color contains the following pigments:
PY35—Cadmium Yellow
Pigment Type
inorganic, cadmium
Chemical Name
cadmium zinc sulfide
Chemical Formula
CdZnS
Properties
Cadmium Yellow is brilliant, dense, and opaque, with good tinting strength and very high hiding power. It is the artist’s principal bright yellow and is available in light, medium, and dark shades. The deeper shades appear deep orange and have the greatest tinting strength. It is slow-drying in oil form and is used in both oil and watercolor form. It cannot be mixed with copper-based pigments. A clean Cadmium Orange is created when Cadmium Yellow is mixed with Cadmium Red. Hues vary by brand. Cadmium pigments have been partially replaced by azo pigments, which are similar in lightfastness to the cadmium colors, cheaper, and non-toxic.
Cadmium Yellow is usually available in a pure grade, or in a cadmium-barium mix. This mix has the same permanence with a lower tinting strength.
Permanence
Cadmium Yellow is lightfast and permanent in most forms, but like most cadmium colors, it will fade in fresco or mural painting. The deeper shades are the most permanent. The pale varieties have been known to fade with exposure to sunlight in conditions where moisture is able to penetrate the binder.
Toxicity
Cadmium Yellow is a known human carcinogen. It can be hazardous if chronically inhaled or ingested.
History
Cadmiums get their names from the Latin word cadmia meaning zinc ore calamine, and the Greek word kadmeia, meaning Cadmean earth, first found near Thebes, the city founded by the Phoenician prince Cadmus. Metallic cadmium was discovered in 1817 by Friedrich Strohmeyer. Oil colors were first made from Cadmium Yellow pigments in 1819, replacing toxic Chrome (lead) Yellows. However, their production was delayed until 1840 due to the scarcity of cadmium metals. Landscape painters, such as Claude Monet, preferred Cadmium Yellow to the less expensive Chrome Yellow because of its higher chroma and greater purity of color.
Alternate Names
Aurora Yellow, Cadmium Primrose Yellow, Cadmium Zinc Yellow, Lemon Yellow, Primrose Yellow. Deep Cadmium Yellow is sometimes called Orient Yellow.
PY74—Hansa Yellow
Pigment Type
monoazo
Chemical Name
n/a
Chemical Formula
C18H18N4O6
Properties
Pigment PY74 is one of the most commercially important pigments of the Hansa Yellow group, considered superior to many others in its class based on both tinting strength and lightfastness. Several PY74 grades with different particle sizes are available. Grades with finer particle size are more brilliant and transparent. Pigment PY74 ranges from reddish yellow to greenish yellow, with temperature shifts from cool to warm hues. It has high tinting strength and average to slow drying time.
Permanence
This Hansa Yellow has better lightfastness that other yellow monoazo pigments, particularly in the darker shades.
Toxicity
Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.
History
Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.
Alternate Names
Arylide, Arylide Yellow, Azo, Brilliant Yellow, Monoazo, Monolite Yellow, Permanent Yellow.
PY65—Hansa Yellow
Pigment Type
monoazo
Chemical Name
n/a
Chemical Formula
C18H18N4O6
Properties
This Hansa Yellow ranges from reddish yellow to greenish yellow with temperature shifts from cool to warm hues. It has good tinting strength and average to slow drying time.
Permanence
This Hansa Yellow has excellent lightfastness, particularly in the darker shades.
Toxicity
Hansa Yellow has no significant acute hazards, though its chronic hazards have not been well studied.
History
Hansa Yellows were first made in Germany just before WW1 from a series of synthetic dyestuffs called Pigment Yellow. They were intended to be a synthetic replacement for Cadmium Yellow.
Alternate Names
Arylide, Arylide Yellow, Azo, Brilliant Yellow, Monoazo, Monolite Yellow, Permanent Yellow.
PW6—Titanium White
Pigment Type
inorganic
Chemical Name
titanium dioxide
Chemical Formula
TiO2
Properties
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Permanence
Titanium White has excellent permanence and lightfastness.
Toxicity
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
History
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Alternate Names
None.
