Color Swatch created using heavy application/medium application/50% tint and was applied on acrylic primed canvas (7 oz) material.
This color contains the following pigments:
PW5—Lithopone
Pigment Type
inorganic
Chemical Name
coprecipitated zinc sulphide and barium sulphate
Chemical Formula
Zn + BaSO4
Properties
Lithopone is a low tinting strength, semi-transparent white pigment that is often used as a filler or extender in other colors, or as the base for laked pigments.
Permanence
Lithopone is absolutely permanent and lightfast.
Toxicity
Lithopone is not toxic.
History
Lithopone was discovered by G.F. de Doubet in 1850. It was developed commercially in the 1870s as a substitute or supplement for lead carbonate, to overcome the many shortcomings of white lead pigment, including toxicity, poor weathering, and darkening in the presence of sulfur compounds. It is used most often in interior paints and enamels. Its use as a white pigment has been superceeded in many applications by titanium dioxide.
Alternate Names
Transparent White.
PV19—Quinacridone Violet
Pigment Type
organic synthetic, quinacridone
Chemical Name
n/a
Chemical Formula
C20H12N2O2
Properties
Quinacridone Red is a high performance, transparent pigment with an average drying time and uneven dispersal. It is another name for Quinacridone Violet (PV19) and Quinacridone Red (PR192). Quinacridone pigments have relatively low tinting strength in general. For this reason, quinacridone colors are often expensive, because more pigment is required in the formulation.
Permanence
Quinacridone Violet has excellent lightfastness and is considered the most lightfast organic pigment in this shade range.
Toxicity
Quinacridone Violet has no known acute hazards. Overexposure to quinacridone pigments may cause skin irritation. Quinicridone pigments contain a compound found to be a skin, eye, and respiratory irritant.
History
Although quinacridone compounds became known in the late 19th century, methods of manufacturing so as to make them practical for use as commercial pigments did not begin until the 1950s. Quinacridone pigments were first developed as coatings for the automotive industry, but were quickly adopted by artists.
Alternate Names
Quinacridone Red (PR192), Quinacridone Red (PR19).
PW6—Titanium White
Pigment Type
inorganic
Chemical Name
titanium dioxide
Chemical Formula
TiO2
Properties
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Permanence
Titanium White has excellent permanence and lightfastness.
Toxicity
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
History
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Alternate Names
None.
PY42—Yellow Ochre
Pigment Type
n/a
Chemical Name
iron(III)-oxide, hydrated
Chemical Formula
Fe2O3 • H2O
Properties
Yellow Ochre provides artists with earthtones from cream to brown. It has good hiding power, produces a quick drying paint, and can be safely mixed with other pigments. Its transparency varies widely from opaque shades to more transparent ones, which are valued for their use as glazes. If gypsum is present, Yellow Ochre is not suitable for frescoing. (See Brown Ochre, PY43.) PY42 is made from synthetic iron oxides. PY43 is made from natural iron oxide.
Permanence
Yellow Ochre has excellent permanence because ochres are some of the most permanent pigments available.
Toxicity
Yellow Ochre is non-toxic unless it contains manganese.
History
Ochre comes from the Greek word ochros, meaning pale yellow. It was one of the first pigments to be used by human beings, and evidence of its use has been found at 300,000 year old sites in France and the former Czechoslovakia.
Alternate Names
Chamois, Iron Yellow, Mars Orange, Mars Yellow, Minette, Ochre, Sil, Yellow Earth, Yellow Oxide. Varieties of Yellow Ochre include Brown Ochre, Flesh Ochre, Roman Ochre, Spruce Ochre, and Transparent Gold Ochre.
