Color Swatch created using heavy application/medium application/50% tint and was applied on acrylic primed canvas (7 oz) material.
This color contains the following pigments:
PG7—Phthalo Green
Pigment Type
organic
Chemical Name
polychlorinated copper(II) phthalocyanine
Chemical Formula
C32H3Cl13CuN8 to C32HCl15CuN8 or C32H16CuN8Cl15 (PG7) or C32Br6Cl10CuN8 (PG36)
Properties
Phthalo Green is a transparent, cool, bright, high intensity color used in oil and acrylics. It comes from a Phthalocyanine Blue pigment where most of the hydrogen atoms have been replaced with chlorine, forming highly stable molecules. It has similar pigment properties and permanence to Phthalo Blue. It is slow drying and an excellent base color for mixing a range of bright greens. Phthalo Green is considered a very good alternative to Viridian because it is intense and mixes well and can be used to emphasize mineral colors in various tints. However, its tinting strength is very high, so it can overpower other colors. This pigment most closely resembles the discontinued and toxic Verdigris.
Permanence
Phthalo Greens are completely lightfast and resistant to alkali, acids, solvents, heat, and ultraviolet radiation. They are currently used in inks, coatings, and many plastics due to their stability and are considered a standard pigment in printing ink and the packaging industry.
Toxicity
Phthalo Green has no significant hazards, but it contained PCBs (polychlorinated biphenyls) until 1982.
History
This bright blue-green was developed in 1935 and has been in use since 1938.
Alternate Names
Bocour Green, Cyan Green, Intense Green, Monastral Green, Phthalocyanine Green, Rembrandt Green, Thalo Green, Winsor Green.
PY1—Hansa Yellow G
Pigment Type
organic, monoazo
Chemical Name
n/a
Chemical Formula
C17H16N4O4
Properties
This Hansa yellow is a transparent yellow. It has great brightness and tinting strength and its drying time ranges from average to slow.
Hansa Yellow makes more intense tints and cleaner secondaries than Cadmium Yellows, especially when mixed with other organic or modern colors like Phthalo Blue and Green. Because they are more transparent, they have great value as glazing colors.
Permanence
Hansa Yellow G has good permanence and lightfastness, particularly in the lighter shades.
Toxicity
Hansa Yellow pigments have no significant acute hazards, though chronic hazards have not been well studied.
History
Hansa Yellows were first made in Germany just before World War I from a series of synthetic dyestuffs called Pigment Yellow. Hansa Yellow G, introduced in 1910, was the first of these products to be commercialized. Hansa Yellow G was the standard yellow for printing inks until late in the 20th century, when stronger diarylide yellows began to replace it. It is still used a great deal in packaging, and for air drying paints.
Alternate Names
Light Fast Yellow G, Pigment Yellow G, Arylide, Arylide Yellow, Azo Yellow, Brilliant Yellow, Monoazo Yellow, Monolite Yellow, Permanent Yellow.
PBk9—Ivory Black
Pigment Type
charred animal bone
Chemical Name
carbon + calcium phosphate
Chemical Formula
C + Ca3(PO4)2 or C × CaPO4
Properties
Ivory Black is a cool, semi-transparent blue-black with a slight brownish undertone and average tinting strength. It mixes well with any color, and creates a range of dull greens when mixed with yellow. It has good properties for use in oil, can be slow to dry in oil form, and should never be used in underpainting or frescoing. Ivory Black is denser than Lamp Black.
Permanence
Ivory Black is very lightfast and has good permanence, though it is considered the least permanent of the major black pigments.
Toxicity
Ivory Black has no significant hazards.
History
Ivory Black is a carbon based black first named as Elephantium, and described in the 4th century BCE as produced by heating ivory scraps in clay pots to reduce the ivory or bone to charcoal. The deviation in names is because the more expensive varieties of this pigment were made by burning ivory, and the less expensive ones by burning animal bone. In the 19th century, the name Ivory Black was finally permitted to be applied to Carbon Black pigments made from bone. True Ivory Black is rare in modern times due to the protection of ivory, and the synthetic variety produced today was discovered in 1929. Bone Black is produced as an industrial pigment.
Alternate Names
Animal Black, Blue Black, Bone Black. Paris Black is an inferior grade of Ivory Black. Incorrectly labeled as Frankfort Black.
PW6—Titanium White
Pigment Type
inorganic
Chemical Name
titanium dioxide
Chemical Formula
TiO2
Properties
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Permanence
Titanium White has excellent permanence and lightfastness.
Toxicity
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
History
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Alternate Names
None.
