Color Swatch created using heavy application/medium application/50% tint and was applied on acrylic primed canvas (7 oz) material.
This color contains the following pigments:
PBr7—Raw Sienna
Pigment Type
earth
Chemical Name
hydrated iron oxide
Chemical Formula
α-FeO3+(OH) or Fe2O3
Properties
Raw Sienna is a moderately dull deep earth yellow with medium tinting strength and excellent transparency. It is one of the basic permanent artists' pigments and is made from a form of limonite clay whose yellow-brown color results from ferric oxides. Raw Sienna is preferable to Yellow Ochre for creating flesh tones, due to its higher subtlety of color when mixed with white. It creates a bright Ochre when mixed with Cadmium Yellow and creates greens and grays when mixed with Ultramarine. Raw Sienna dries quickly.
Permanence
Raw Sienna has good permanence.
Toxicity
Raw Sienna has no significant hazards.
History
Raw Sienna has been used as a pigment since prehistoric times, although its current name came about during the Renaissance. It comes from the city of Siena, in Italy, and is short for terra di Siena, meaning earth of Siena. Sienna was famous for the mining and production of earth pigments from the Renaissance until World War II. Due to the depletion of clay deposits in Tuscany, Italian siennas now come from other areas, including Sicily and Sardinia.
Alternate Names
Italian Earth, Natural Brown Iron Oxide, Sienna.
PBk11—Mars Black
Pigment Type
earth
Chemical Name
iron oxides
Chemical Formula
FeO or Fe2O3
Properties
Mars Black is an opaque black with a strong and cool masstone, a slightly warm tint, and a warm brown undertone. It is not as black as Ivory Black, but it dries more quickly and has three times the tinting strength. Mars Black is normally the only black available in acrylic form and that is safe to over paint. It can be used in all media without reservation and is widely used as an alternative to Lamp Black and Ivory Black.
Permanence
Mars Black is very lightfast with excellent permanence.
Toxicity
Mars Black has no significant hazards and is the only major black pigment considered non-toxic.
History
The word Mars refers to the Roman god of iron and war. Mars Black was developed in the early 20th century from inorganic, synthetic iron oxide.
Alternate Names
Black Iron Oxide, Iron Black, Magnetic Oxide, Mapico Black, Mineral Black. Sometimes labeled as Vine Black.
PBk7—Lamp Black
Pigment Type
inorganic
Chemical Name
carbon
Chemical Formula
C
Properties
Lamp black is a very opaque, heavily staining black pigment that does not have much covering or tinting power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures. Natural sources may be brownish or bluish in tone because of impurities. When used in oil paints, it is one of the slowest drying pigments, and should not be used in underpainting or applied in layers underneath other colors.
Permanence
Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.
Toxicity
Carbon itself is not considered hazardous, however other combustion products that are hazardous are often present as impurities when Lamp Black is produced from natural materials. For this reason, commercial preparations of the pigment should be considered slightly toxic. Avoid skin contact and inhalation. Where such impurities are present, Lamp Black is a possible human carcinogen.
History
Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It has been used as a pigment since prehistoric times. It is the black found in Egyptian murals and tomb decorations and was the most popular black for fresco painting until the development of Mars Black.
Alternate Names
Carbon Black, Channel Black, Furnace Black, Oil Black, Vegetable Black. Flame Black is an impure version of Lamp Black. An alternate spelling is Lampblack, in which the first syllable is stressed and the two words are elided to form a closed compound.
