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Each pure pigment is ground to its correct degree of fineness and formulated individually under exacting controls. Permanent and free from darkening, yellowing, fading, and cracking. Also Basic Set.
Color Swatches created using heavy application/medium application/50% tint and were applied on acrylic primed canvas (7 oz) material.
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Titanium White has excellent permanence and lightfastness.
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Fe7(CN)18(H2O)x or C6FeN6H4N
Prussian Blue is a semi-transparent, deep cyan-blue with a greenish undertone and a very high tinting strength unequaled by most pigments. It is similar to Phthalo Blue unless mixed with white, when it gives up intensity and becomes smoky. It can behave erratically and less reliably in oil and watercolor form depending on its manufacture. For permanent painting Phthalo Blue is considered a more reliable choice.
Prussian Blue is lightfast and permanent in all techniques except for fresco. When mixed with Zinc White in watercolor or tempera form, it fades upon exposure to light and completely regains its chromatic strength in the dark. Modern manufacturing techniques have made this tendency less of an issue in recent years
Prussian Blue is moderately toxic if ingested. It will emit toxic hydrogen cyanide gas if heated, exposed to ultraviolet radiation, or treated with acid.
"The first of the modern pigments," Prussian Blue is the first artificial pigment with a known history. It was discovered by accident in 1704 by the Berlin color maker Heinrich Diesbach, who was trying to create a pigment with a red hue by mixing iron sulfate and potash. The potash Diesbach purchased from a local laboratory had been contaminated by animal oil and blood during previous experimentation. The resulting mixture yielded a very pale red that changed to purple and then deep blue when he tried to concentrate it. Since previous blue pigments came from lapis lazuli, an expensive stone, Diesbach’s discovery was extremely important for artists of the time.
Berlin Blue, Bronze Blue, Iron Blue, Paris Blue, Paste Blue. Celestial Blue, Monthier Blue and Soluble Blue are varieties of Prussian Blue. Blue Lake is a reduced or let-down variety of Prussian Blue. Chinese Blue, Milori Blue, and Steel Blue are the three highest grades of Prussian Blue.
iron oxides with manganese silicates or dioxide
Fe2O3,MnO2 or Fe2O3 + MnO2 + nH2O + Si + Al2O3
Burnt Umber is a more intense reddish brown pigment that results from heating the clay pigment Raw Umber. It has medium to excellent tinting strength and high opacity, and it is quick drying in oil form. Burnt Umber is somewhat more transparent than Raw Umber. It has excellent color properties and can create a variety of subtle, clear tints when mixed with white. It can tend towards chalkiness in dark mixes in oil form, but overall it mixes well with other colors. To create a black color in oil form, mix Burnt Umber with Phthalo Blue or Ultramarine. To achieve a similar color in watercolor form, mix it with Ultramarine or Payne's Gray.
Burnt Umber has good permanence.
Burnt Umber itself is considered non-toxic. If contaminated by manganese compounds, it may be highly toxic if inhaled and moderately toxic if ingested.
This pigment gets its name from the Latin word umbra, meaning shadow or shade. Its full name is listed as terra di ombra, meaning earth of shadow/shade, due to its original extraction from the area of Umbria, Italy. It has been used as a pigment since prehistoric times. Currently, the finest umber comes from Cyprus.
Chestnut Brown, Euchrome, Jacaranda Brown, Mars Brown, Mineral Brown, Raw Brown, Spanish Brown, Van Dyke Umber. Cyprus Umber, Turkey Brown, and Turkey Umber are the best quality umbers.
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