Color Swatch created using heavy application/diluted application and was applied on cold press watercolor paper (150 lb) material.
This color contains the following pigments:
PG23—Green Earth
Pigment Type
earth
Chemical Name
hydrated iron, magnesium, aluminum and potassium silicates
Chemical Formula
K[(Al,FeIII),(FeII,Mg)](AlSi3,Si4)O10(OH)2
Properties
Green earth is a natural pigment that varies from yellow and olive to blue-green in its composition and hues. It is semi-transparent, has low hiding power and tinting strength, muddies and darkens in oil, and is particularly good for tempera and fresco painting.
Permanence
Green Earth has excellent permanence and lightfastness, although some varieties can be developed by light calcining. It is one of the most permanent pigments because Earths are not affected by sunlight or atmospheric conditions.
Toxicity
Green Earth has no significant hazards.
History
Terre verte is French for green earth. It was discovered in antiquity, and its use has been traced to the Ajanta caves in India and a variety of Roman sites, including Pompeii. Green Earth was very popular for underpainting flesh tones in medieval paintings because this green was the compliment to pink on the medieval color wheel. Its use declined after the Renaissance. The natural supplies of the pigment are mostly depleted, and manufacturers currently duplicate the hue using mineral bases like Viridian, iron oxide, or chromium oxide, or artificial ceramic colorants. Pigments sold under this name can also be the result of mixing Sienna and Phthalo Green.
Alternate Names
Celadon Green, Celadonite. Green Bice, Holly Green, Stone Green, Terra Verte, Verdeterra, Verdetta, Veronese Green. Bohemian Earth is a high quality, clear, middle-green variety. Cyprus Green Earth, or Cyprian, is a high quality yellowish variety. Tyrolean and Verona Earth are high quality bluish varieties. Verona Brown is a calcinated variation of Green Earth. Burnt Green Earth is similar to Transparent Brown
PW4—Zinc White
Pigment Type
inorganic
Chemical Name
zinc(II)-oxide
Chemical Formula
ZnO
Properties
Zinc White is the coolest white, and it has a cold, clean masstone and a slightly bluish tint. It has less hiding power and is more transparent than other whites. It dries slowly and is good for painting wet into wet and for glazing and scumbling. Zinc White is neither as opaque nor as heavy as Lead White, its covering power is not as good, and it takes much longer to dry. However, it does not blacken when exposed to sulfur in the air as Lead White does. It is very valuable for making tints with other colors. Unmixed Zinc White dries to a brittle and dry paint film that may crack over the years, so it is not good for frescoing. It is more transparent in acrylic form than Titanium White and is the most commonly used white with gouache. Chinese White is a version of Zinc White appropriate for opaque watercolor techniques.
Permanence
Zinc White has great permanence and lightfastness.
Toxicity
Zinc White is moderately toxic if ingested and slightly toxic if inhaled.
History
Though historians are divided on who first isolated the element zinc, they agree that it was first suggested as a white pigment in 1782. Zinc White was accepted as a watercolor in 1834 and was called Chinese White due to the popularity of oriental porcelain in Europe at the time. Ten years later, a suitable oil form was produced. By the early 20th century, it had improved to the point where it was an acceptable alternative to Flake White.
Alternate Names
Chinese White, French White, Permanent White, Silver White, Snow White, Zinc Oxide.
PBr7—Raw Sienna
Pigment Type
earth
Chemical Name
hydrated iron oxide
Chemical Formula
α-FeO3+(OH) or Fe2O3
Properties
Raw Sienna is a moderately dull deep earth yellow with medium tinting strength and excellent transparency. It is one of the basic permanent artists' pigments and is made from a form of limonite clay whose yellow-brown color results from ferric oxides. Raw Sienna is preferable to Yellow Ochre for creating flesh tones, due to its higher subtlety of color when mixed with white. It creates a bright Ochre when mixed with Cadmium Yellow and creates greens and grays when mixed with Ultramarine. Raw Sienna dries quickly.
Permanence
Raw Sienna has good permanence.
Toxicity
Raw Sienna has no significant hazards.
History
Raw Sienna has been used as a pigment since prehistoric times, although its current name came about during the Renaissance. It comes from the city of Siena, in Italy, and is short for terra di Siena, meaning earth of Siena. Sienna was famous for the mining and production of earth pigments from the Renaissance until World War II. Due to the depletion of clay deposits in Tuscany, Italian siennas now come from other areas, including Sicily and Sardinia.
Alternate Names
Italian Earth, Natural Brown Iron Oxide, Sienna.
PW6—Titanium White
Pigment Type
inorganic
Chemical Name
titanium dioxide
Chemical Formula
TiO2
Properties
Titanium White is the most brilliant of the white pigments. It is considered an all purpose oil color useful in all techniques and the best all around white. Its masstone is neither warm nor cool, placing it somewhere between Lead White and Zinc White. It is less prone to cracking and yellowing than Lead White, but it still yellows easily. Titanium White dries slowly in oil form, more slowly than Lead White but more quickly than Zinc White. It is opaque in oil and acrylic forms and semi-opaque in watercolor form. This pigment has good chemical stability, and its tinting strength is superior to both Lead White and Zinc White.
Permanence
Titanium White has excellent permanence and lightfastness.
Toxicity
Titanium dioxide is highly stable and is regarded as completely non-toxic. Animal studies give no indiciation that it is absorbed biologically, even after long periods of exposure. The primary safety concern is with inhalation of fine pigment dust particles. Titanium White, if inhaled in large amounts over the course of several years, may cause a benign pneumoconiosis that is visible on x-rays. The National Institute of Occupational Safety and Health (NIOSH) considers fine titanium dioxide particles, if inhaled, to be a human carcinogen. The primary concern for artists is to avoid exposure to fine particulate dust from raw pigments.
History
Titanium is the ninth most abundant element in the Earth's crust, however mineral deposits that are economical to mine are less common. Titanium dioxide was first discovered in 1821, although it could not be mass produced until 1919. Widespread use of the pigment began in the 1940s. Since that time, it has become the most commonly used white pigment. The name comes from the Latin word Titan, the name for the elder brother of Kronos and ancestor of the Titans, and from the Greek word tito, meaning day or sun.
Alternate Names
None.
PBk7—Lamp Black
Pigment Type
inorganic
Chemical Name
carbon
Chemical Formula
C
Properties
Lamp black is a very opaque, heavily staining black pigment that does not have much covering or tinting power. It is typically the most opaque black in watercolor form. Though a very pure black, it tends to muddy slightly in mixtures. Natural sources may be brownish or bluish in tone because of impurities. When used in oil paints, it is one of the slowest drying pigments, and should not be used in underpainting or applied in layers underneath other colors.
Permanence
Lamp Black is very lightfast and absolutely permanent. It is used in all techniques in permanent painting.
Toxicity
Carbon itself is not considered hazardous, however other combustion products that are hazardous are often present as impurities when Lamp Black is produced from natural materials. For this reason, commercial preparations of the pigment should be considered slightly toxic. Avoid skin contact and inhalation. Where such impurities are present, Lamp Black is a possible human carcinogen.
History
Lamp Black is a carbon based black traditionally produced by collecting soot (known as lampblack) from oil lamps. It has been used as a pigment since prehistoric times. It is the black found in Egyptian murals and tomb decorations and was the most popular black for fresco painting until the development of Mars Black.
Alternate Names
Carbon Black, Channel Black, Furnace Black, Oil Black, Vegetable Black. Flame Black is an impure version of Lamp Black. An alternate spelling is Lampblack, in which the first syllable is stressed and the two words are elided to form a closed compound.